Functionalized Polyisobutylene and Polyisobutylene‐Based Block Copolymers by Mechanistic Transformation from Cationic to Radical Process
Abstract The strategy for the preparation of polyisobutylene‐based block copolymers via mechanistic transformation from cationic to radical polymerization is reported. This strategy involves the synthesis of 2‐bromo‐2‐methylpropanoyl‐terminated difunctional polyisobutylene macroinitiator (BiBB‐PIB‐BiBB) via consecutive cationic polymerization, in situ preparation of hydroxyl‐terminated polyisobutylene and its acylation by 2‐bromo‐2‐methylpropanoyl bromide. The Mn 2 (CO) 10 −triggered photo‐induced radical polymerization of styrene in bulk using this macroinitiator leads to the formation of multiblock copolymer, while predominantly triblock copolymer is generated during the polymerization of methyl methacrylate. The possibility to functionalize the polyisobutylene by pyrene via photo‐induced radical addition of 1‐bromomethyl pyrene in the presence of Mn 2 (CO) 10 is also demonstrated in this work.
Authors
- Barış Kışkan (ORCID: https://orcid.org/0000-0001-9476-2054)
- Tugba Celiker (ORCID: https://orcid.org/0000-0002-7796-1462)
- Maksim I. Hulnik
- Yusra Bahar Cakir (ORCID: https://orcid.org/0000-0002-0793-6798)
- Miraslau I. Makarevich (ORCID: https://orcid.org/0000-0003-4324-1296)
- Mikalai Bohdan
- Sergei V. Kostjuk (ORCID: https://orcid.org/0000-0002-7466-3662)
- Irina V. Vasilenko (ORCID: https://orcid.org/0000-0002-4270-188X)
Institutions
- Sechenov University (RU)
- Belarusian State University (BY)
- Istanbul Technical University (TR)
Publication Details
- Journal
- Macromolecular Chemistry and Physics
- Published
- 2024-09-10
- DOI
- https://doi.org/10.1002/macp.202400261
- Citations
- 2
- Primary Topic
- Advanced Polymer Synthesis and Characterization
- Type
- article
- Field-Weighted Citation Impact
- 0.50
Funders
- Türkiye Bilimsel ve Teknolojik Araştırma Kurumu
- Yükseköğretim Kurulu
- Istanbul Teknik Üniversitesi
- Ministry of Science and Higher Education of the Russian Federation
- I.M. Sechenov First Moscow State Medical University
- Ulusal Metroloji Enstitüsü, Türkiye Bilimsel ve Teknolojik Araştirma Kurumu
- Bilimsel Araştırma Projeleri Birimi, İstanbul Teknik Üniversitesi