Role of Organic Vapor Precursors in Secondary Organic Aerosol Formation: Concurrent Observations of IVOCs and VOCs in Guangzhou

Abstract Secondary organic aerosol (SOA) formed through the atmospheric transformation of organic vapors constitutes a significant portion of fine particulate matter or PM 2.5 . While recent laboratory studies underscore the importance of intermediate‐volatility organic compounds (IVOCs) as key precursors to SOA, field observations that recognize the role of both volatile organic compounds (VOCs) and IVOCs in SOA formation remain scarce. In this study, we conducted concurrent measurements of VOCs and IVOCs in ambient air at urban and suburban sites in Guangzhou during a PM 2.5 pollution event in winter 2021. The results reveal that between 12:00–15:00 local time, the photochemically adjusted initial concentrations of VOCs at both sites were approximately 7 times higher than that of IVOCs. However, the SOA formation potential (SOAFP) of primary hydrocarbon IVOCs exceeded that of VOCs by over 3–4 times. Receptor modeling results further indicated that while ship emissions contributed to less than 10% of the C2–C22 primary hydrocarbons concentration (VOCs + primary carbonaceous IVOCs), they accounted for the most significant source (approximately 40%) of SOA formation. This study highlights the substantial role of IVOCs in SOA formation and emphasizes the importance of future PM 2.5 pollution control measures targeting major IVOCs contributors, such as ship emissions in harbor cities.