The Effect of Nitrogen on the Dihedral Angle Between Fe−Ni Melt and Ringwoodite: Implications for the Nitrogen Deficit in the Bulk Silicate Earth

Abstract Nitrogen (N) is extremely depleted in the bulk silicate Earth (BSE). However, whether the silicate magma ocean was as N‐poor as the present‐day BSE is unknown. We performed multi‐anvil experiments at 20 GPa and 1,673−2,073 K to determine the dihedral angle of Fe−Ni−N alloy melt in ringwoodite matrix to investigate whether percolation of Fe‐rich alloy melt in the solid mantle can explain N depletion in the BSE. The dihedral angles ranged from 112° to 137°, surpassing the wetting boundary. Our experiments suggest that N removal from the mantle by percolation of Fe‐rich alloy melt to the Earth's core is unlikely. Therefore, besides N loss to space during planetesimal and planetary differentiation, as well as its segregation into the Earth core, the stranded Fe‐rich metal in the deep mantle could be a hidden N reservoir, contributing to the anomalous depletion of N in the observable BSE.

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Publication Details

Journal
Geophysical Research Letters
Published
2024-09-10
DOI
https://doi.org/10.1029/2024gl109584
Citations
3
Primary Topic
Geological and Geochemical Analysis
Type
article
Field-Weighted Citation Impact
1.60

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article

The Effect of Nitrogen on the Dihedral Angle Between Fe−Ni Melt and Ringwoodite: Implications for the Nitrogen Deficit in the Bulk Silicate Earth

Kurt Leinenweber, Damanveer S. Grewal, A. Wittmann, Sang‐Heon Shim et al.
3 citations
Geophysical Research Letters
Geological and Geochemical Analysis
1.60
article

The Effect of Nitrogen on the Dihedral Angle Between Fe−Ni Melt and Ringwoodite: Implications for the Nitrogen Deficit in the Bulk Silicate Earth

Kurt Leinenweber, Damanveer S. Grewal, A. Wittmann, Sang‐Heon Shim, Logan J. Leinbach, K. Tsuno, Virginia Xu
article en
3 citations

Abstract

Abstract Nitrogen (N) is extremely depleted in the bulk silicate Earth (BSE). However, whether the silicate magma ocean was as N‐poor as the present‐day BSE is unknown. We performed multi‐anvil experiments at 20 GPa and 1,673−2,073 K to determine the dihedral angle of Fe−Ni−N alloy melt in ringwoodite matrix to investigate whether percolation of Fe‐rich alloy melt in the solid mantle can explain N depletion in the BSE. The dihedral angles ranged from 112° to 137°, surpassing the wetting boundary. Our experiments suggest that N removal from the mantle by percolation of Fe‐rich alloy melt to the Earth's core is unlikely. Therefore, besides N loss to space during planetesimal and planetary differentiation, as well as its segregation into the Earth core, the stranded Fe‐rich metal in the deep mantle could be a hidden N reservoir, contributing to the anomalous depletion of N in the observable BSE.

Geophysical Research LettersVol. 51(18)
Arizona State University (US)
National Science Foundation, Arizona State University, Eyring Materials Center, Arizona State University, Division of Electrical, Communications and Cyber Systems, Division of Earth Sciences
Openalex Percentile: Top 19%
Geological and Geochemical Analysis
1.60
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