The Effect of Nitrogen on the Dihedral Angle Between Fe−Ni Melt and Ringwoodite: Implications for the Nitrogen Deficit in the Bulk Silicate Earth
Abstract Nitrogen (N) is extremely depleted in the bulk silicate Earth (BSE). However, whether the silicate magma ocean was as N‐poor as the present‐day BSE is unknown. We performed multi‐anvil experiments at 20 GPa and 1,673−2,073 K to determine the dihedral angle of Fe−Ni−N alloy melt in ringwoodite matrix to investigate whether percolation of Fe‐rich alloy melt in the solid mantle can explain N depletion in the BSE. The dihedral angles ranged from 112° to 137°, surpassing the wetting boundary. Our experiments suggest that N removal from the mantle by percolation of Fe‐rich alloy melt to the Earth's core is unlikely. Therefore, besides N loss to space during planetesimal and planetary differentiation, as well as its segregation into the Earth core, the stranded Fe‐rich metal in the deep mantle could be a hidden N reservoir, contributing to the anomalous depletion of N in the observable BSE.
Authors
- Kurt Leinenweber (ORCID: https://orcid.org/0000-0001-9243-0494)
- Damanveer S. Grewal (ORCID: https://orcid.org/0000-0002-5653-1543)
- A. Wittmann (ORCID: https://orcid.org/0000-0001-7572-0801)
- Sang‐Heon Shim (ORCID: https://orcid.org/0000-0001-5203-6038)
- Logan J. Leinbach (ORCID: https://orcid.org/0009-0009-5910-9004)
- K. Tsuno (ORCID: https://orcid.org/0000-0002-4577-227X)
- Virginia Xu
Institutions
- Arizona State University (US)
Publication Details
- Journal
- Geophysical Research Letters
- Published
- 2024-09-10
- DOI
- https://doi.org/10.1029/2024gl109584
- Citations
- 3
- Primary Topic
- Geological and Geochemical Analysis
- Type
- article
- Field-Weighted Citation Impact
- 1.60
Funders
- National Science Foundation
- Arizona State University
- Eyring Materials Center, Arizona State University
- Division of Electrical, Communications and Cyber Systems
- Division of Earth Sciences