Ultrafast reaction kinetic of polyaniline in flexible hydrogel electrodes facilitated by graphene ribbons

Abstract By loading energy storage active materials on hydrogel which is inherently flexible, the flexibility of electrode materials can be simply realized, thereby achieving the flexibility of energy storage devices. However, the polymer network that constructs the three-dimensional skeleton of the hydrogel is not conductive, which inhibits the redox ability of the active material. If a high speed conductive structure can be added to the colloidal phase, the performance of the flexible electrode material can be greatly improved. Here, we introduce redox graphene ribbons into the polyvinyl alcohol hydrogel loaded with polyaniline. The in situ three-dimensional conductive graphene network greatly enhanced the conductivity of the hydrogel electrode, thus increasing the specific capacitance to as high as 1117 F g −1 at 2 mg cm −2 mass loading, with a retention ratio of 66.96% from 0.5 A g −1 to 20 A g −1 . These highlighted properties enable the PRP hydrogel as an electrode for flexible supercapacitors, which provides a promising possibility for the practical application of wearable electronics.