Measuring linear birefringence via rotating-sample transmission Stokes spectropolarimetry

Linear birefringence is a fundamental property of optically anisotropic media, defined by the difference in refractive index experienced by light polarized along orthogonal directions. It is usually manifested in microscopically aligned molecular systems, where a preferential direction of light–matter interaction is created. For instance, the anisotropic structure of calcite crystal causes the famous double-refraction phenomenon. Another common example is commercial adhesive tapes, which are polymeric materials possessing birefringent properties due to their manufacturing processes. The intrinsic relation between birefringence and molecular alignment forges a new analytical route to study materials such as polymeric thin films. Therefore, the capacity of measuring linear birefringence and its fast axis is of paramount importance for the science of anisotropic molecular systems. In this contribution, a comprehensive approach to acquire linear birefringence using rotating-sample transmission Stokes spectropolarimetry is presented and applied to transparent adhesive tapes as a case study. The experimental setup comprises a thermal light source and a spectropolarimeter capable of determining wavelength distributions of Stokes parameters. The samples are carefully aligned in a rotating mount and subjected to a fixed broadband vertically polarized light beam. Then, the transmitted light is analyzed using a rotating retarder type of spectropolarimeter. Through systematic variation of the sample’s angular position, the Stokes parameters of transmitted light are measured for each transmitted wavelength as a function of the sample’s angular position. The linear retardance and fast axis direction relative to the tape’s long axis are then determined from the modulation of Stokes parameters over sample rotation. The model derivation, experimental procedure, and signal processing protocol are described in detail, and the approach is verified with a simple correlation between linear retardance and the number of stacked layers of tape.