Heat Capacity and Thermodynamic Functions of Yb2O3⋅2HfO2 Solid Solution

A sample of Yb2O3⋅2HfO2 solid solution is synthesized and characterized via X-ray diffraction, electron microscopy, and chemical analysis. Relaxation, adiabatic, and differential scanning calorimetry are used to measure the isobaric heat capacity of the sample in the range of 2.4–1807 K, and thermodynamic functions are calculated with allowance for the contribution from low-temperature transformation. The Schottky anomaly’s contribution to the heat capacity in the region of 2.4–300 K is determined.

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Publication Details

Journal
Russian Journal of Physical Chemistry A
Published
2024-09-01
DOI
https://doi.org/10.1134/s0036024424701036
Citations
1
Primary Topic
Nuclear materials and radiation effects
Type
article
Field-Weighted Citation Impact
0.12
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article

Heat Capacity and Thermodynamic Functions of Yb2O3⋅2HfO2 Solid Solution

А. Хорошилов, V. N. Guskov, A. V. Guskov, П. Г. Гагарин et al.
1 citations
Russian Journal of Physical Chemistry A
Nuclear materials and radiation effects
0.12
article

Heat Capacity and Thermodynamic Functions of Yb2O3⋅2HfO2 Solid Solution

А. Хорошилов, V. N. Guskov, A. V. Guskov, П. Г. Гагарин, К. С. Гавричев
article en
1 citations

Abstract

A sample of Yb2O3⋅2HfO2 solid solution is synthesized and characterized via X-ray diffraction, electron microscopy, and chemical analysis. Relaxation, adiabatic, and differential scanning calorimetry are used to measure the isobaric heat capacity of the sample in the range of 2.4–1807 K, and thermodynamic functions are calculated with allowance for the contribution from low-temperature transformation. The Schottky anomaly’s contribution to the heat capacity in the region of 2.4–300 K is determined.

Russian Journal of Physical Chemistry AVol. 98(9)
NS Kurnakova Institute of General and Inorganic Chemistry (RU)
Affordable and clean energy
Openalex Percentile: Top 60%
Nuclear materials and radiation effects
0.12
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