Thermodynamic Limit of the Free Electron Gas on a Circle

We show that for the ground state of a one-dimensional free electron gas on a circle the analytic expression for the canonical ensemble partition function can be easily derived from the density matrix by assuming that the thermodynamic limit coincides with the limit of the eigenfunction expansion of the kinetic energy. This approximation fails to give the finite temperature partition function because those two limits cannot be chosen as coincident.

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Publication Details

Journal
The Physics Educator
Published
2024-09-01
DOI
https://doi.org/10.1142/s2661339524500124
Primary Topic
Quantum, superfluid, helium dynamics
Type
article
Field-Weighted Citation Impact
0.00
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article

Thermodynamic Limit of the Free Electron Gas on a Circle

Riccardo Fantoni
The Physics Educator
Quantum, superfluid, helium dynamics
article

Thermodynamic Limit of the Free Electron Gas on a Circle

Riccardo Fantoni
article en

Abstract

We show that for the ground state of a one-dimensional free electron gas on a circle the analytic expression for the canonical ensemble partition function can be easily derived from the density matrix by assuming that the thermodynamic limit coincides with the limit of the eigenfunction expansion of the kinetic energy. This approximation fails to give the finite temperature partition function because those two limits cannot be chosen as coincident.

The Physics EducatorVol. 06(03)
University of Trieste (IT)
Affordable and clean energy
Openalex Percentile: Top 87%
Quantum, superfluid, helium dynamics
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Thermodynamic Limit of the Free Electron Gas on a Circle — Riccardo Fantoni · The Physics Educator (2024) | TGRS Research Map | TGRS