<i>catena</i>-Poly[[(8-aminoquinoline)cobalt(II)]-di-μ-azido]
The title coordination polymer, [Co(N<sub>3</sub>)<sub>2</sub>(C<sub>9</sub>H<sub>8</sub>N<sub>2</sub>)] <sub><i>n</i></sub> , was synthesized solvothermally. The Co<sup>II</sup> atom exhibits a distorted octa-hedral [CoN<sub>6</sub>] coordination geometry with a bidentate 8-amino-quinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100]. N-H⋯N hydrogen bonds join the chains to give an extended structure with sheets parallel to (002).
Authors
- Mohammed Hadi Al–Douh (ORCID: https://orcid.org/0000-0001-9777-2653)
- Abderezak Addala
- Zouaoui Setifi (ORCID: https://orcid.org/0000-0002-8160-3852)
- David K. Geiger (ORCID: https://orcid.org/0000-0002-6168-8756)
- Fatima Setifi (ORCID: https://orcid.org/0000-0002-9860-9310)
Institutions
- SUNY Geneseo (US)
- Hadhramout University (YE)
- University Ferhat Abbas of Setif (DZ)
- University of Skikda (DZ)
Publication Details
- Journal
- IUCrData
- Published
- 2024-09-06
- DOI
- https://doi.org/10.1107/s2414314624008496
- Citations
- 1
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.12
Funders
- Direction Générale de la Recherche Scientifique et du Développement Technologique