Bis[2-(isoquinolin-1-yl)phenyl-κ<sup>2</sup> <i>N</i>,<i>C</i> <sup>1</sup>](2-phenyl-1<i>H</i>-imidazo[4,5-<i>f</i>][1,10]phenanthroline-κ<sup>2</sup> <i>N</i>,<i>N</i>′)iridium(III) hexafluoridophosphate methanol monosolvate
The title compound, [Ir(C<sub>15</sub>H<sub>10</sub>N)<sub>2</sub>(C<sub>19</sub>H<sub>12</sub>N<sub>4</sub>)]PF<sub>6</sub>·CH<sub>3</sub>OH, crystallizes in the <i>C</i>2/<i>c</i> space group with one monocationic iridium complex, one hexa-fluorido-phosphate anion, and one methanol solvent mol-ecule of crystallization in the asymmetric unit, all in general positions. The anion and solvent are linked to the iridium complex cation <i>via</i> hydrogen bonding. All bond lengths and angles fall into expected ranges compared to similar compounds.
Authors
- William W. Brennessel (ORCID: https://orcid.org/0000-0001-5461-1825)
- Carly R. Reed (ORCID: https://orcid.org/0000-0003-0268-1017)
- A. Hasan
- Silas Martin
Institutions
- SUNY Brockport (US)
- University of Rochester (US)
Publication Details
- Journal
- IUCrData
- Published
- 2024-09-06
- DOI
- https://doi.org/10.1107/s2414314624008599
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Science Foundation
- State University of New York
- University of Rochester
- Brockport Foundation
- Division of Chemistry