Highly Efficient Continuous Flow Nanocatalyst Platform Constructed with Regenerable Bacterial Cellulose Loaded with Gold Nanoparticles and a Nanoporous Membrane

With the development of society and the growing concern about environmental issues, continuous flow catalytic reactors have gained significant interest due to their resource-efficient advantages over traditional batch devices. In this study, we employed a facile one-step in situ reduction approach to construct highly dispersed gold nanoparticles loaded on regenerable bacterial cellulose nanofiber (BCN) heterogeneous catalysts. These catalysts, in combination with a nanoceramic membrane with a pore size of 1 nm, formed a fully mixed system that was favorable for the efficient continuous flow catalysis of selective reduction reactions of nitrophenol. The reaction system demonstrated remarkable catalytic activity toward nitrophenol reduction reactions at low reductant dosages (<5 equiv), achieving over 95% conversion and 99% selectivity for the aniline product in 10 min under room temperature conditions. Furthermore, continuous flow operations maintained stable catalytic activity with minimal catalyst loss after a 120-h test and were 3 times more time-efficient than batch operations. Additionally, continuous monitoring could be conducted through ultraviolet (UV) spectroscopy. A highly efficient and environmentally friendly strategy was present for designing continuous flow reactions in future applications.