Figure-Eight Bismacrocycles Derived from a Tetraphenylmethane Core and Oligoparaphenylene Loops

Cycloparaphenylenes have garnered significant interest due to their distinctive chemical and physical characteristics. This study presents the synthesis and comprehensive characterization of two bis-macrocycle molecules joined by cycloparaphenylene and tetraphenylmethane moieties. Both molecules were thoroughly characterized using NMR, MALDI-TOF-HRMS, and X-ray diffraction. UV-vis spectroscopy revealed maximum absorption peaks at 325 and 328 nm, while the two bismacrocycles exhibit fluorescence emissions at 470 and 457 nm, consistent with DFT calculations. The computational analysis also disclosed the HOMO-LUMO gaps of 3.373 and 3.342 eV.