Rhodium‐Catalyzed Synthesis of Polycyclic Spiroindolines via Intramolecular 1,2‐Acyloxy Migration‐Cyclization Cascade
Abstract Herein, a novel and efficient protocol for the synthesis of polycyclic spiroindolines is realized through a 1,2‐acyloxy migration‐cyclization cascade starting from ester‐tethered 1,2,3‐triazoles. [6,5,5,6] and [6,5,6,6] ring skeleton are constructed in moderate to excellent yields.
Authors
- Ze‐Feng Xu (ORCID: https://orcid.org/0000-0002-4531-6266)
- Chuan‐Ying Li (ORCID: https://orcid.org/0000-0001-9400-6830)
- Jing Chen (ORCID: https://orcid.org/0000-0002-0024-4561)
- Mingming Yu (ORCID: https://orcid.org/0009-0007-4705-7548)
- Zhuoya Chen
Institutions
- Zhejiang Sci-Tech University (CN)
Publication Details
- Journal
- European Journal of Organic Chemistry
- Published
- 2024-09-06
- DOI
- https://doi.org/10.1002/ejoc.202400944
- Citations
- 4
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 1.00