Research on Alkali-Activated Slag Stabilization of Dredged Silt Based on a Response Surface Method

To improve the resource utilization of dredged silt and industrial waste, this study explores the efficacy of using ground granulated blast furnace slag (GGBS), active calcium oxide (CaO), and sodium silicate (Na<sub>2</sub>O·nSiO<sub>2</sub>) as alkali activators for silt stabilization. Through a combination of addition tests, response surface method experiments, and microscopic analyses, we identified key factors influencing the unconfined compressive strength (UCS) of stabilized silt, optimized material ratios, and elucidated stabilization mechanisms. The results revealed the following: (1) CaO exhibited the most pronounced stabilization effect, succeeded by Na<sub>2</sub>O·nSiO<sub>2</sub>, whereas GGBS alone displayed marginal efficacy. CaO-stabilized silt demonstrated rapid strength augmentation within the initial 7 d, while Na<sub>2</sub>O·nSiO<sub>2</sub>-stabilized silt demonstrated a more gradual strength enhancement over time, attributable to the delayed hydration of GGBS in non-alkaline conditions, with strength increments noticeably during later curing phases. (2) Response surface analysis demonstrated substantial interactions among GGBS-CaO and GGBS-Na<sub>2</sub>O·nSiO<sub>2</sub>, with the optimal dosages identified as 11.5% for GGBS, 4.1% for CaO, and 5.9% for Na<sub>2</sub>O·nSiO<sub>2</sub>. (3) X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses clarified that the hydration reactions within the GGBS-Na<sub>2</sub>O·nSiO<sub>2</sub> composite cementitious system synergistically enhanced one another, with hydration products wrapping, filling, and binding the silt particles, thereby rendering the microstructure denser and more stable. Based on these experimental outcomes, we propose a microstructural mechanism model for the stabilization of dredged silt employing GGBS-CaO-Na<sub>2</sub>O·nSiO<sub>2</sub>.

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Publication Details

Journal
Materials
Published
2024-09-06
DOI
https://doi.org/10.3390/ma17174410
Citations
5
Primary Topic
Concrete and Cement Materials Research
Type
article
Field-Weighted Citation Impact
1.30

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article

Research on Alkali-Activated Slag Stabilization of Dredged Silt Based on a Response Surface Method

Gaoliang Tao, Wei Yao, Qizhi Hu
5 citations
Materials
Concrete and Cement Materials Research
1.30
article

Research on Alkali-Activated Slag Stabilization of Dredged Silt Based on a Response Surface Method

Gaoliang Tao, Wei Yao, Qizhi Hu
article en
5 citations

Abstract

To improve the resource utilization of dredged silt and industrial waste, this study explores the efficacy of using ground granulated blast furnace slag (GGBS), active calcium oxide (CaO), and sodium silicate (Na<sub>2</sub>O·nSiO<sub>2</sub>) as alkali activators for silt stabilization. Through a combination of addition tests, response surface method experiments, and microscopic analyses, we identified key factors influencing the unconfined compressive strength (UCS) of stabilized silt, optimized material ratios, and elucidated stabilization mechanisms. The results revealed the following: (1) CaO exhibited the most pronounced stabilization effect, succeeded by Na<sub>2</sub>O·nSiO<sub>2</sub>, whereas GGBS alone displayed marginal efficacy. CaO-stabilized silt demonstrated rapid strength augmentation within the initial 7 d, while Na<sub>2</sub>O·nSiO<sub>2</sub>-stabilized silt demonstrated a more gradual strength enhancement over time, attributable to the delayed hydration of GGBS in non-alkaline conditions, with strength increments noticeably during later curing phases. (2) Response surface analysis demonstrated substantial interactions among GGBS-CaO and GGBS-Na<sub>2</sub>O·nSiO<sub>2</sub>, with the optimal dosages identified as 11.5% for GGBS, 4.1% for CaO, and 5.9% for Na<sub>2</sub>O·nSiO<sub>2</sub>. (3) X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses clarified that the hydration reactions within the GGBS-Na<sub>2</sub>O·nSiO<sub>2</sub> composite cementitious system synergistically enhanced one another, with hydration products wrapping, filling, and binding the silt particles, thereby rendering the microstructure denser and more stable. Based on these experimental outcomes, we propose a microstructural mechanism model for the stabilization of dredged silt employing GGBS-CaO-Na<sub>2</sub>O·nSiO<sub>2</sub>.

MaterialsVol. 17(17)
Hubei University of Technology (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 22%
Concrete and Cement Materials Research
1.30
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Research on Alkali-Activated Slag Stabilization of Dredged Silt Based on a Response Surface Method — Gaoliang Tao, Wei Yao, et al. · Materials (2024) | TGRS Research Map | TGRS