Experimental study of pargasite NaCa<sub>2</sub> (Mg<sub>4</sub>Al)[Si<sub>6</sub>Al<sub>2</sub>O<sub>22</sub>](OH)<sub>2</sub> stability at T = 1000–1100°C and the pressure is u

The paper presents materials on experimental study of pargasite stability. On the example of calcic amphibole, experimental modeling of the processes occurring in the conditions of volcanic hearth at pressures up to 5 kbar was carried out. The phase diagram of pargasite was clarified. The occurring reactions and their parameters are revealed. Based on the experimental data obtained, the stability of pargasite is controlled by three reactions. The first reaction takes place in the area of low water pressure less than 1 kbar – dehydration reaction:Prg = Fo + Sp + Di + Ne + An +H2O. The second reaction takes place in the area of water pressure more than 1.2-1.5 kbar and temperature around 1100°C. Pargasite decomposition is controlled by incongruent melting:Prg = Fo + Sp +{Di+Ne +An}L+H2O. The third reaction takes place in the same pressure range as the previous one, but at lower temperatures ~1050°C. This reaction determines the pargasite liquidus in the melt and is related to the interaction between the amphibole and the coexisting melt:Prg + L= Fo + Sp + Di +{Ne +Pl}L+H2O.Presumably, the activity of the melt silicaaSiO2has the greatest impact on the pargasite liquidus.

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Publication Details

Journal
Геохимия
Published
2024-09-06
DOI
https://doi.org/10.31857/s0016752524020035
Primary Topic
High-pressure geophysics and materials
Type
article
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article

Experimental study of pargasite NaCa2 (Mg4Al)[Si6Al2O22](OH)2 stability at T = 1000–1100°C and the pressure is u

V. N. Devyatova, Г. В. Бондаренко, A. N. Nekrasov
Геохимия
High-pressure geophysics and materials
article

Experimental study of pargasite NaCa2 (Mg4Al)[Si6Al2O22](OH)2 stability at T = 1000–1100°C and the pressure is u

V. N. Devyatova, Г. В. Бондаренко, A. N. Nekrasov
article en

Abstract

The paper presents materials on experimental study of pargasite stability. On the example of calcic amphibole, experimental modeling of the processes occurring in the conditions of volcanic hearth at pressures up to 5 kbar was carried out. The phase diagram of pargasite was clarified. The occurring reactions and their parameters are revealed. Based on the experimental data obtained, the stability of pargasite is controlled by three reactions. The first reaction takes place in the area of low water pressure less than 1 kbar – dehydration reaction:Prg = Fo + Sp + Di + Ne + An +H2O. The second reaction takes place in the area of water pressure more than 1.2-1.5 kbar and temperature around 1100°C. Pargasite decomposition is controlled by incongruent melting:Prg = Fo + Sp +{Di+Ne +An}L+H2O. The third reaction takes place in the same pressure range as the previous one, but at lower temperatures ~1050°C. This reaction determines the pargasite liquidus in the melt and is related to the interaction between the amphibole and the coexisting melt:Prg + L= Fo + Sp + Di +{Ne +Pl}L+H2O.Presumably, the activity of the melt silicaaSiO2has the greatest impact on the pargasite liquidus.

ГеохимияVol. 69(2)
Institute of Experimental Mineralogy (RU)
Openalex Percentile: Top 84%
High-pressure geophysics and materials
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