Construction of coral reef-like transition/rare earth metal oxide-supported gC3N4-based nanocomposite: A new approach for enhanced visible light-assisted photocatalytic removal of orange G dye

Industrial wastewater contains harmful substances such as antibiotics, chemical fertilizers, heavy metals, dyes, and pesticides. Photocatalysis is a simple and efficient way to remove these pollutants using visible light. The study reports the potential enhancement of ZnO's photocatalytic activity with Dy 2 O 3 supported on a 2-dimensional coral reef-like nanostructure. ZnO is also safer and more affordable, making it a good choice for improved photocatalytic and antimicrobial applications. In a standard synthesis, metal and rare earth metal nitrates were combined with a 2D carbon-based material and synthesized using co-precipitation. FE-SEM and XRD were utilized to characterize the DZG nanocomposite, revealing its morphology and crystallinity. FT-IR analysis detected the presence of the M-O bond, and the band gap was measured using UV-DRS analysis. The as-prepared nanocomposite exhibited enhanced photocatalytic capabilities under visible light irradiation for degrading orange G dye (OG). The preliminary and kinetic studies have confirmed that the prepared DZG nanocomposite exhibits increased photocatalytic activity. Results indicate that DZG has better photocatalytic activity (PCA) than g-C 3 N 4 , and the reaction followed pseudo-first-order degradation kinetics. The f-shells in dysprosium oxide trap the excited electrons, extend the electron-hole pair (EHP) recombination process, and enhance photocatalytic activity. The UV–visible spectroscopy measurements showed that the DZG 1:25 nanocomposite completely degraded OG in the water. • Rare-earth metal oxide and Zinc oxide -supported carbon-based material synthesized by co-precipitation method. • The photocatalytic activity of the prepared catalyst was examined against frequently used orange G (OG). • The photocatalytic degradation of OG achieves 99.25 % efficiency under visible light irradiation.

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Publication Details

Journal
Applied Catalysis O Open
Published
2024-09-06
DOI
https://doi.org/10.1016/j.apcato.2024.207009
Citations
4
Primary Topic
Advanced Photocatalysis Techniques
Type
article
Field-Weighted Citation Impact
0.41
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article

Construction of coral reef-like transition/rare earth metal oxide-supported gC3N4-based nanocomposite: A new approach for enhanced visible light-assisted photocatalytic removal of orange G dye

G.A. Suganya Josephine, S. Rubesh Ashok Kumar, B. Dhanalakshmi, Vasvini Mary D et al.
4 citations
Applied Catalysis O Open
Advanced Photocatalysis Techniques
0.41
article

Construction of coral reef-like transition/rare earth metal oxide-supported gC3N4-based nanocomposite: A new approach for enhanced visible light-assisted photocatalytic removal of orange G dye

G.A. Suganya Josephine, S. Rubesh Ashok Kumar, B. Dhanalakshmi, Vasvini Mary D, Jennifer G. Joseph
article en
4 citations

Abstract

Industrial wastewater contains harmful substances such as antibiotics, chemical fertilizers, heavy metals, dyes, and pesticides. Photocatalysis is a simple and efficient way to remove these pollutants using visible light. The study reports the potential enhancement of ZnO's photocatalytic activity with Dy 2 O 3 supported on a 2-dimensional coral reef-like nanostructure. ZnO is also safer and more affordable, making it a good choice for improved photocatalytic and antimicrobial applications. In a standard synthesis, metal and rare earth metal nitrates were combined with a 2D carbon-based material and synthesized using co-precipitation. FE-SEM and XRD were utilized to characterize the DZG nanocomposite, revealing its morphology and crystallinity. FT-IR analysis detected the presence of the M-O bond, and the band gap was measured using UV-DRS analysis. The as-prepared nanocomposite exhibited enhanced photocatalytic capabilities under visible light irradiation for degrading orange G dye (OG). The preliminary and kinetic studies have confirmed that the prepared DZG nanocomposite exhibits increased photocatalytic activity. Results indicate that DZG has better photocatalytic activity (PCA) than g-C 3 N 4 , and the reaction followed pseudo-first-order degradation kinetics. The f-shells in dysprosium oxide trap the excited electrons, extend the electron-hole pair (EHP) recombination process, and enhance photocatalytic activity. The UV–visible spectroscopy measurements showed that the DZG 1:25 nanocomposite completely degraded OG in the water. • Rare-earth metal oxide and Zinc oxide -supported carbon-based material synthesized by co-precipitation method. • The photocatalytic activity of the prepared catalyst was examined against frequently used orange G (OG). • The photocatalytic degradation of OG achieves 99.25 % efficiency under visible light irradiation.

Applied Catalysis O OpenVol. 195
Vinayaka Missions University (IN)
Life below water
Openalex Percentile: Top 48%
Advanced Photocatalysis Techniques
0.41
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