Construction of coral reef-like transition/rare earth metal oxide-supported gC3N4-based nanocomposite: A new approach for enhanced visible light-assisted photocatalytic removal of orange G dye
Industrial wastewater contains harmful substances such as antibiotics, chemical fertilizers, heavy metals, dyes, and pesticides. Photocatalysis is a simple and efficient way to remove these pollutants using visible light. The study reports the potential enhancement of ZnO's photocatalytic activity with Dy 2 O 3 supported on a 2-dimensional coral reef-like nanostructure. ZnO is also safer and more affordable, making it a good choice for improved photocatalytic and antimicrobial applications. In a standard synthesis, metal and rare earth metal nitrates were combined with a 2D carbon-based material and synthesized using co-precipitation. FE-SEM and XRD were utilized to characterize the DZG nanocomposite, revealing its morphology and crystallinity. FT-IR analysis detected the presence of the M-O bond, and the band gap was measured using UV-DRS analysis. The as-prepared nanocomposite exhibited enhanced photocatalytic capabilities under visible light irradiation for degrading orange G dye (OG). The preliminary and kinetic studies have confirmed that the prepared DZG nanocomposite exhibits increased photocatalytic activity. Results indicate that DZG has better photocatalytic activity (PCA) than g-C 3 N 4 , and the reaction followed pseudo-first-order degradation kinetics. The f-shells in dysprosium oxide trap the excited electrons, extend the electron-hole pair (EHP) recombination process, and enhance photocatalytic activity. The UV–visible spectroscopy measurements showed that the DZG 1:25 nanocomposite completely degraded OG in the water. • Rare-earth metal oxide and Zinc oxide -supported carbon-based material synthesized by co-precipitation method. • The photocatalytic activity of the prepared catalyst was examined against frequently used orange G (OG). • The photocatalytic degradation of OG achieves 99.25 % efficiency under visible light irradiation.
Authors
- G.A. Suganya Josephine
- S. Rubesh Ashok Kumar (ORCID: https://orcid.org/0009-0004-7825-7209)
- B. Dhanalakshmi
- Vasvini Mary D
- Jennifer G. Joseph
Institutions
- Vinayaka Missions University (IN)
Publication Details
- Journal
- Applied Catalysis O Open
- Published
- 2024-09-06
- DOI
- https://doi.org/10.1016/j.apcato.2024.207009
- Citations
- 4
- Primary Topic
- Advanced Photocatalysis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.41