Effects of difference in heating sources on ammonia reactivity: Possibility for photolysis-assisted ammonia combustion

• Measured NH 3 reactivity significantly changed with different reactor heat sources. • Ultraviolet light from a hydrogen flame could enhance NH 3 reactivity through photolysis. • Photolysis-assisted ammonia combustion could overcome low reactivity of NH 3 . Ammonia (NH 3 ) reactivity in a micro flow reactor with a controlled temperature profile (MFR) is reexamined through species measurements utilizing two heating sources in the MFR: an H 2 /air flat flame and an electric heater. The maximum wall temperatures ( T w, max ) formed in the reactor vary in a range of T w, max = 1100–1400 K. A stoichiometric NH 3 /air mixture is tested, and exhaust NH 3 is detected by a quadrupole mass spectrometer (QMS). Unexpectedly, NH 3 is completely consumed at temperatures at least 100 K lower in the H 2 /air flat flame case compared to the electric furnace case, despite nearly identical conditions of a MFR characteristic residence time estimated by the wall temperature profiles and the convective flow velocity. Considering the non-thermal characteristics of the two heating sources that the H 2 /air flat flame emits ultraviolet light, whereas infrared light as thermal radiation is emitted within the electric furnace, the possibility of NH 3 photolysis in the H 2 /air flat flame case is discussed based on literature regarding emissions from the H 2 /air flames, the transmittance of the quartz tube, and the photodissociation of NH 3 in the ultraviolet region. When ultraviolet light emitted from the H 2 /air flat flame passes through the quartz tube and decomposes NH 3 into NH 2 and H radicals, these produced radicals enhance the growth of OH radicals, resulting in increased NH 3 reactivity. These findings suggest the possibility of photolysis-assisted ammonia combustion, which could be an additional method to overcome the low reactivity of NH 3 .