Interpolating the radial distribution function in a two-dimensional fluid across a wide temperature range
Calculations of pair correlations in fluids usually require resource-intensive simulations or integral equations, while existing simple approximations lack accuracy. Here, we show that the pair correlation function for monolayer fluid-like systems can be decomposed into correlation peaks defined using Voronoi cells. Being properly normalized, these peaks exhibit a universal form, weak temperature dependence, and resemble those of an ideal gas, except for the first peak. As a result, we propose a simple and accurate approach to interpolate the pair correlation functions, suitable for molecular, colloids, and cellular fluids.
Authors
- Artur D. Nasyrov
- Stanislav O. Yurchenko (ORCID: https://orcid.org/0000-0001-6821-904X)
- Nikita P. Kryuchkov (ORCID: https://orcid.org/0000-0002-9085-1284)
- Ilya R. Denisenko
Institutions
- Bauman Moscow State Technical University (RU)
Publication Details
- Journal
- The Journal of Chemical Physics
- Published
- 2024-09-05
- DOI
- https://doi.org/10.1063/5.0213689
- Citations
- 5
- Primary Topic
- Material Dynamics and Properties
- Type
- article
- Field-Weighted Citation Impact
- 0.59
Funders
- Russian Science Foundation