Earth stabilisation with MgO-based cement

This study compares, for the first time, MgO-based (MB) cement and Portland-based (PB) cement for stabilizing earth mortars. While MB and PB earth mortars reach similar strength, MB cement stabilization demonstrates superior early-age performance. Thermogravimetric analysis, X-ray diffraction, 29 Si and 31 P NMR spectroscopies show that the cement reacts in both systems and allow to establish the phase assemblages. The stabilized earth pastes contain less hydroxide phases, indicating a pozzolanic reaction in both cases. MB-stabilized clay mortars retain about 1/3 of the compressive strength of pure MB mortar, while with PB this proportion is only 1/5. This difference demonstrates that MB is more compatible with clay minerals and more suitable for stabilizing earth mortars. If MB cement could be produced with renewable energy from CO 2 -free sources (instead of from magnesite), stabilization of earth mortars with MB would be substantially more CO 2 efficient than with PB.

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Publication Details

Journal
Cement and Concrete Research
Published
2024-09-05
DOI
https://doi.org/10.1016/j.cemconres.2024.107655
Citations
13
Primary Topic
Magnesium Oxide Properties and Applications
Type
article
Field-Weighted Citation Impact
1.52

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article

Earth stabilisation with MgO-based cement

Daniel Rentsch, Ellina Bernard, Guillaume Habert, Pietro Lura et al.
13 citations
Cement and Concrete Research
Magnesium Oxide Properties and Applications
1.52
article

Earth stabilisation with MgO-based cement

Daniel Rentsch, Ellina Bernard, Guillaume Habert, Pietro Lura, Raphael Kuhn
article en
13 citations

Abstract

This study compares, for the first time, MgO-based (MB) cement and Portland-based (PB) cement for stabilizing earth mortars. While MB and PB earth mortars reach similar strength, MB cement stabilization demonstrates superior early-age performance. Thermogravimetric analysis, X-ray diffraction, 29 Si and 31 P NMR spectroscopies show that the cement reacts in both systems and allow to establish the phase assemblages. The stabilized earth pastes contain less hydroxide phases, indicating a pozzolanic reaction in both cases. MB-stabilized clay mortars retain about 1/3 of the compressive strength of pure MB mortar, while with PB this proportion is only 1/5. This difference demonstrates that MB is more compatible with clay minerals and more suitable for stabilizing earth mortars. If MB cement could be produced with renewable energy from CO 2 -free sources (instead of from magnesite), stabilization of earth mortars with MB would be substantially more CO 2 efficient than with PB.

Cement and Concrete ResearchVol. 186
ETH Zurich (CH), Institute for Biomedical Engineering (CH), Infrastructure Management Consultants (Switzerland) (CH), Swiss Finance Institute (CH), Swiss Federal Laboratories for Materials Science and Technology (CH)
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Openalex Percentile: Top 14%
Magnesium Oxide Properties and Applications
1.52
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