Luminescent Mn<sup>2+</sup>-Doped MgO–Al<sub>2</sub>O<sub>3</sub>–ZrO<sub>2</sub>–SiO<sub>2</sub> Sol-Gel Materials

In present work Mn2+-doped MgO-Al2O3-ZrO2-SiO2 materials were synthesized. Their structure, morphology, chemical composition and luminescent properties were studied using X-Ray diffraction, scanning electron microscopy, EDX analysis and luminecent spectroscopy. It was shown that the application of sol-gel method provides the high-volume homogeneity of chemical composition of synthesized materials. Introduction of Mn into the composition of sol-gel materials accelerates significantly the crystalization processes during the thermal treatment. In the luminescence spectra several groups of emission bands are observed. These bands are situated in blue and yellow-red part of spectrum. this phenomenon is related with incorporation of Mn2+ into the structure of different crystals formed during the thermal treatment of gels. Obtained materials can be perspective for application as luminophores in the lighting for plant production.

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Publication Details

Journal
Журнал неорганической химии
Published
2024-09-05
DOI
https://doi.org/10.31857/s0044457x24030134
Primary Topic
Luminescence Properties of Advanced Materials
Type
article
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article

Luminescent Mn2+-Doped MgO–Al2O3–ZrO2–SiO2 Sol-Gel Materials

D. A. Yurchenko, S. K. Evstropiev, D. V. Bulyga, N. B. Knyazyan et al.
Журнал неорганической химии
Luminescence Properties of Advanced Materials
article

Luminescent Mn2+-Doped MgO–Al2O3–ZrO2–SiO2 Sol-Gel Materials

D. A. Yurchenko, S. K. Evstropiev, D. V. Bulyga, N. B. Knyazyan, А. С. Саратовский, Konstantin V. Dukelskii, V. L. Stolyarova
article en

Abstract

In present work Mn2+-doped MgO-Al2O3-ZrO2-SiO2 materials were synthesized. Their structure, morphology, chemical composition and luminescent properties were studied using X-Ray diffraction, scanning electron microscopy, EDX analysis and luminecent spectroscopy. It was shown that the application of sol-gel method provides the high-volume homogeneity of chemical composition of synthesized materials. Introduction of Mn into the composition of sol-gel materials accelerates significantly the crystalization processes during the thermal treatment. In the luminescence spectra several groups of emission bands are observed. These bands are situated in blue and yellow-red part of spectrum. this phenomenon is related with incorporation of Mn2+ into the structure of different crystals formed during the thermal treatment of gels. Obtained materials can be perspective for application as luminophores in the lighting for plant production.

Журнал неорганической химииVol. 69(3)
St Petersburg University (RU), ITMO University (RU), Saint-Petersburg State University of Telecommunications (RU), Czech Academy of Sciences, Institute of Inorganic Chemistry (CZ), Institute of Chemistry of Silicates named after I.V. Grebenshchikov (RU), State Optical Institute named after SI Vavilov (RU), St. Petersburg State Technological Institute (RU)
Openalex Percentile: Top 91%
Luminescence Properties of Advanced Materials
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