Modularly Precise Construction of B,N-Embedded Large-Sized Polycyclic Aromatic Hydrocarbon Nanographene
A modular "fjord-stitching" reverse strategy has been disclosed to successfully prepare two large-sized B,N-embedded nanographenes: BN-TBTi and BN-TBTo. These two compounds both exhibit excellent stability, nonzero-bandgap and decent photoluminescence quantum yield. Single crystal structure of BN-TBTo features a large C<sub>78</sub>B<sub>2</sub>N<sub>4</sub> π-skeleton with length and width of approximately 2.4 and 1.5 nm, respectively.
Authors
- Yupei Qu
- Yincai Xu (ORCID: https://orcid.org/0000-0003-4163-0802)
- Jianan Xue
- Yue Wang (ORCID: https://orcid.org/0000-0001-6936-5081)
- Qingyang Wang (ORCID: https://orcid.org/0000-0002-1709-2680)
- Cheng Qu (ORCID: https://orcid.org/0000-0003-3909-9119)
- Tingting Huang
Institutions
- Jilin University (CN)
- Ji Hua Laboratory (CN)
- State Key Laboratory of Supramolecular Structure and Materials
Publication Details
- Journal
- Organic Letters
- Published
- 2024-09-04
- DOI
- https://doi.org/10.1021/acs.orglett.4c02611
- Citations
- 1
- Primary Topic
- Graphene research and applications
- Type
- article
- Field-Weighted Citation Impact
- 0.12
Funders
- National Natural Science Foundation of China
- Foshan Science and Technology Bureau
- Jihua Laboratory
- National Key Research and Development Program of China