Photochemistry of cyanoacetylene in solid argon revisited
Isotopic (2H and 15N) labelling and IR absorption spectroscopy have been used to study UV-induced transformations of cyanoacetylene in cryogenic noble gas matrices. The results obtained indicate that all observed isomerization processes involve single, isolated molecules of the precursor. No photoproducts have been found that would imply the recombination of fragments originating from different molecules.
Authors
- Thomas Custer (ORCID: https://orcid.org/0000-0003-2336-4248)
- Arun‐Libertsen Lawzer (ORCID: https://orcid.org/0000-0002-6020-1256)
- Claudine Crépin (ORCID: https://orcid.org/0000-0002-7478-5643)
- Marcin Gronowski (ORCID: https://orcid.org/0000-0002-7547-4548)
- Robert Kołos (ORCID: https://orcid.org/0000-0001-6103-9660)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université Paris-Saclay (FR)
- Institut des Sciences Moléculaires d'Orsay (FR)
- Institute of Physical Chemistry (PL)
- University of Warsaw (PL)
- Polish Academy of Sciences (PL)
Publication Details
- Journal
- Low Temperature Physics
- Published
- 2024-09-01
- DOI
- https://doi.org/10.1063/10.0028163
- Primary Topic
- Inorganic Fluorides and Related Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00