Mechanical and optical properties assessment of an innovative PDMS/beeswax composite for a wide range of applications

Polydimethylsiloxane (PDMS) is an elastomer that has received primary attention from researchers due to its excellent physical, chemical, and thermal properties, together with biocompatibility and high flexibility properties. Another material that has been receiving attention is beeswax because it is a natural raw material, extremely ductile, and biodegradable, with peculiar hydrophobic properties. These materials are applied in hydrophobic coatings, clear films for foods, and films with controllable transparency. However, there is no study with a wide range of mechanical, optical, and wettability tests, and with various proportions of beeswax reported to date. Thus, we report an experimental study of these properties of pure PDMS with the addition of beeswax and manufactured in a multifunctional vacuum chamber. In this study, we report in a tensile test a 37% increase in deformation of a sample containing 1% beeswax (BW1%) when compared to pure PDMS (BW0%). The Shore A hardness test revealed a 27% increase in the BW8% sample compared to BW0%. In the optical test, the samples were subjected to a temperature of 80 °C and the BW1% sample increased 30% in transmittance when compared to room temperature making it as transparent as BW0% in the visible region. The thermogravimetric analysis showed thermal stability of the BW8% composite up to a temperature of 200 °C. The dynamic mechanical analysis test revealed a 100% increase in the storage modulus of the BW8% composite. Finally, in the wettability test, the composite BW8% presented a contact angle with water of 145°. As a result of this wide range of tests, it is possible to increase the hydrophobic properties of PDMS with beeswax and the composite has great potential for application in smart devices, food and medicines packaging films, and films with controllable transparency, water-repellent surfaces, and anti-corrosive coatings.

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Publication Details

Journal
Journal of the mechanical behavior of biomedical materials/Journal of mechanical behavior of biomedical materials
Published
2024-09-03
DOI
https://doi.org/10.1016/j.jmbbm.2024.106716
Citations
4
Primary Topic
Plant Surface Properties and Treatments
Type
article
Field-Weighted Citation Impact
2.40

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article

Mechanical and optical properties assessment of an innovative PDMS/beeswax composite for a wide range of applications

Andrews Souza, Delfim Soares, Andréa Zille, Ronaldo Ariati et al.
4 citations
Journal of the mechanical behavior of biomedical materials/Journal of mechanical behavior of biomedical materials
Plant Surface Properties and Treatments
2.40
article

Mechanical and optical properties assessment of an innovative PDMS/beeswax composite for a wide range of applications

Andrews Souza, Delfim Soares, Andréa Zille, Ronaldo Ariati, Rui Lima, João Ribeiro, Maria Cecília B. V. de Souza
article en
4 citations

Abstract

Polydimethylsiloxane (PDMS) is an elastomer that has received primary attention from researchers due to its excellent physical, chemical, and thermal properties, together with biocompatibility and high flexibility properties. Another material that has been receiving attention is beeswax because it is a natural raw material, extremely ductile, and biodegradable, with peculiar hydrophobic properties. These materials are applied in hydrophobic coatings, clear films for foods, and films with controllable transparency. However, there is no study with a wide range of mechanical, optical, and wettability tests, and with various proportions of beeswax reported to date. Thus, we report an experimental study of these properties of pure PDMS with the addition of beeswax and manufactured in a multifunctional vacuum chamber. In this study, we report in a tensile test a 37% increase in deformation of a sample containing 1% beeswax (BW1%) when compared to pure PDMS (BW0%). The Shore A hardness test revealed a 27% increase in the BW8% sample compared to BW0%. In the optical test, the samples were subjected to a temperature of 80 °C and the BW1% sample increased 30% in transmittance when compared to room temperature making it as transparent as BW0% in the visible region. The thermogravimetric analysis showed thermal stability of the BW8% composite up to a temperature of 200 °C. The dynamic mechanical analysis test revealed a 100% increase in the storage modulus of the BW8% composite. Finally, in the wettability test, the composite BW8% presented a contact angle with water of 145°. As a result of this wide range of tests, it is possible to increase the hydrophobic properties of PDMS with beeswax and the composite has great potential for application in smart devices, food and medicines packaging films, and films with controllable transparency, water-repellent surfaces, and anti-corrosive coatings.

Journal of the mechanical behavior of biomedical materials/Journal of mechanical behavior of biomedical materialsVol. 160
Universidade do Porto (PT), Universidade Politécnica de Bragança (PT), University of Minho (PT)
Kansainvälisen Liikkuvuuden ja Yhteistyön Keskus, Ministério da Ciência, Tecnologia e Ensino Superior, Fundação para a Ciência e a Tecnologia
Openalex Percentile: Top 11%
Plant Surface Properties and Treatments
2.40
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