Synthesis of V<sub>6</sub>O<sub>13</sub> Supported Catalyst for Intensive Catalytic Oxidative Desulfurization of Diesel

In this work, a mixed-valence vanadium oxide V6O13 nanosheet was successfully prepared and combined with 3D g-C3N4 to build a composite catalyst for the oxidative desulfurization (ODS) system. The consequences of FT-IR, wide-angle XRD, and SEM analyses manifested that the loading capacity had a significant impact on the morphology of the supported catalyst, while a 20% loading amount conduced to the full dispersion of V6O13 without damaging the structure of the carrier. As a result, the obtained catalyst 20% V6O13/3D g-C3N4 exhibited outstanding catalytic ability, and the desulfurization rates for different types of sulfides employed in this work could all reach 100%. In addition, the anti-interference ability, recycling performance, and possible reaction mechanism of the ODS system were also investigated.

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Publication Details

Journal
Energy & Fuels
Published
2024-09-03
DOI
https://doi.org/10.1021/acs.energyfuels.4c02700
Citations
3
Primary Topic
Catalysis and Hydrodesulfurization Studies
Type
article
Field-Weighted Citation Impact
0.64

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article

Synthesis of V6O13 Supported Catalyst for Intensive Catalytic Oxidative Desulfurization of Diesel

Haiyan Ji, Songmei Wang, Wenshuai Zhu, Suhang Xun et al.
3 citations
Energy & Fuels
Catalysis and Hydrodesulfurization Studies
0.64
article

Synthesis of V6O13 Supported Catalyst for Intensive Catalytic Oxidative Desulfurization of Diesel

Haiyan Ji, Songmei Wang, Wenshuai Zhu, Suhang Xun, Junjie Zhang, Minqiang He, Huaming Li, Zengsheng Xie
article en
3 citations

Abstract

In this work, a mixed-valence vanadium oxide V6O13 nanosheet was successfully prepared and combined with 3D g-C3N4 to build a composite catalyst for the oxidative desulfurization (ODS) system. The consequences of FT-IR, wide-angle XRD, and SEM analyses manifested that the loading capacity had a significant impact on the morphology of the supported catalyst, while a 20% loading amount conduced to the full dispersion of V6O13 without damaging the structure of the carrier. As a result, the obtained catalyst 20% V6O13/3D g-C3N4 exhibited outstanding catalytic ability, and the desulfurization rates for different types of sulfides employed in this work could all reach 100%. In addition, the anti-interference ability, recycling performance, and possible reaction mechanism of the ODS system were also investigated.

Energy & FuelsVol. 38(18)
Jiangsu University (CN), Suzhou University of Science and Technology (CN)
National Natural Science Foundation of China, China Postdoctoral Science Foundation, State Key Laboratory of Heavy Oil Processing, Collaborative Innovation Center for Water Treatment Technology and Materials
Openalex Percentile: Top 36%
Catalysis and Hydrodesulfurization Studies
0.64
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