Experimental review and accuracy of etchants used for phase analysis of SAF2507 Super Duplex Stainless Steel

The mechanical and corrosion properties of duplex stainless steels (DSS) depend on the distribution of ferrite and austenite as well as the presence of secondary phases. It is therefore necessary to accurately determine both the distribution of the phases and their morphology. The aim of this research is to define a standard method for the determination of the volume fraction of the phases present in a SAF2507 SDSS by analysing images acquired by light microscope. To do this, the material is heat-treated at 850 °C for 5 min, 15 min, 30 min, 1h, 5h to stimulate the formation of the σ-phase. The metallographic etchant capable of maximising phase contrast is then identified. Micrographic analyses are performed using different reagents at different holding times and temperatures, in order to find the best combination. A standard procedure is then defined for the image analysis. The data obtained were are processed to calculate the phase distribution. The results are compared with the quantitative analysis performed using X-ray diffraction as reference. The research evidence that Kalling's reagent is best etchant for fully solubilised materials, as it accurately estimates ferrite and austenite content. On the other hand, Marble's reagent should be preferred for the detection of σ-phase. For comprehensive analysis of all phases, Murakami's reagent is recommended. The approach defined in this paper not only improves the understanding of the microstructure of DSS, but also provides an important tool for industrial quality control and material characterisation. • The mechanical and corrosion properties of DSS depend on the phase distribution and the presence of secondary phases. • It is important to accurately determine the volume fraction of the phases and their morphology. • The Kalling’s reagent is the best etchant for the evaluation of the ferrite and austenite content in solubilised condition. • The Marble's reagent is preferred to detect only the σ-phase and the Groesbeck’s reagent produces very similar results. • The Murakami's reagent is used to determine all the phases in one time.