Investigation of the cesium activation of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><mml:mrow><mml:mi>Ga</mml:mi><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math> photocathodes by low-ener
Low-energy electron microscopy (LEEM) was performed on $p$-$\mathrm{Ga}\mathrm{N}$ samples during in situ cesium deposition. LEEM images of electron reflectivity recorded as a function of the incident electron energy at different $\mathrm{Cs}$ coverages allowed to spatially resolve the evolution of the local work function (WF) during the activation process. While the average WF drops by more than 3 eV, the local WF remains quite uniform across the surface throughout the activation process. Maximum fluctuations of less than 0.2 eV were observed in the WF maps for $\mathrm{Cs}$ coverage of a fraction of a monolayer. These fluctuations are mainly related to the surface topography, in particular, to the atomic steps' structure, which replicates the substrate miscut. Apart from these weak spatial fluctuations, no $\mathrm{Cs}$ clusters that would induce strong local WF contrast were observed at the scale of the 20-nm resolution of the measurements. These observations agree with the simple model of semiconductor activation to negative electron affinity that describes the formation of a dipole layer as responsible for the lowering of the WF. Additionally, at complete $\mathrm{Cs}$ coverage, the WF becomes fully homogeneous over the surface, smoothing out features originating from defects and topography.
Authors
- Jacques Peretti (ORCID: https://orcid.org/0000-0002-7566-101X)
- Cameron Johnson (ORCID: https://orcid.org/0000-0002-2802-5838)
- Claude Weisbuch (ORCID: https://orcid.org/0000-0001-5403-5274)
- Yi Chao Chow (ORCID: https://orcid.org/0000-0002-8926-0268)
- Wan Ying Ho (ORCID: https://orcid.org/0000-0001-7089-6912)
- Andreas K. Schmid (ORCID: https://orcid.org/0000-0003-0035-3095)
- James S. Speck (ORCID: https://orcid.org/0000-0002-8045-4090)
- Mylène Sauty (ORCID: https://orcid.org/0000-0002-5425-1628)
- Tanay Tak (ORCID: https://orcid.org/0000-0002-6982-5938)
Institutions
- École Polytechnique (FR)
- Lawrence Berkeley National Laboratory (US)
- University of California, Santa Barbara (US)
Publication Details
- Journal
- Physical Review Applied
- Published
- 2024-09-03
- DOI
- https://doi.org/10.1103/physrevapplied.22.034005
- Citations
- 2
- Primary Topic
- Photocathodes and Microchannel Plates
- Type
- article
- Field-Weighted Citation Impact
- 0.37
Funders
- National Science Foundation
- U.S. Department of Energy
- Simons Foundation
- Agence Nationale de la Recherche
- Office of Science
- Office of Energy Efficiency and Renewable Energy
- University of California, Santa Barbara
- Basic Energy Sciences
- Solid State Lighting and Energy Electronics Center, University of California Santa Barbara
- Office of Energy Efficiency
- Core Research for Evolutional Science and Technology