Investigation of the cesium activation of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><mml:mrow><mml:mi>Ga</mml:mi><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math> photocathodes by low-ener

Low-energy electron microscopy (LEEM) was performed on $p$-$\mathrm{Ga}\mathrm{N}$ samples during in situ cesium deposition. LEEM images of electron reflectivity recorded as a function of the incident electron energy at different $\mathrm{Cs}$ coverages allowed to spatially resolve the evolution of the local work function (WF) during the activation process. While the average WF drops by more than 3 eV, the local WF remains quite uniform across the surface throughout the activation process. Maximum fluctuations of less than 0.2 eV were observed in the WF maps for $\mathrm{Cs}$ coverage of a fraction of a monolayer. These fluctuations are mainly related to the surface topography, in particular, to the atomic steps' structure, which replicates the substrate miscut. Apart from these weak spatial fluctuations, no $\mathrm{Cs}$ clusters that would induce strong local WF contrast were observed at the scale of the 20-nm resolution of the measurements. These observations agree with the simple model of semiconductor activation to negative electron affinity that describes the formation of a dipole layer as responsible for the lowering of the WF. Additionally, at complete $\mathrm{Cs}$ coverage, the WF becomes fully homogeneous over the surface, smoothing out features originating from defects and topography.

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Publication Details

Journal
Physical Review Applied
Published
2024-09-03
DOI
https://doi.org/10.1103/physrevapplied.22.034005
Citations
2
Primary Topic
Photocathodes and Microchannel Plates
Type
article
Field-Weighted Citation Impact
0.37

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article

Investigation of the cesium activation of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><mml:mrow><mml:mi>Ga</mml:mi><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math> photocathodes by low-ener

Jacques Peretti, Cameron Johnson, Claude Weisbuch, Yi Chao Chow et al.
2 citations
Physical Review Applied
Photocathodes and Microchannel Plates
0.37
article

Investigation of the cesium activation of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><mml:mrow><mml:mi>Ga</mml:mi><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math> photocathodes by low-ener

Jacques Peretti, Cameron Johnson, Claude Weisbuch, Yi Chao Chow, Wan Ying Ho, Andreas K. Schmid, James S. Speck, Mylène Sauty, Tanay Tak
article en
2 citations

Abstract

Low-energy electron microscopy (LEEM) was performed on $p$-$\mathrm{Ga}\mathrm{N}$ samples during in situ cesium deposition. LEEM images of electron reflectivity recorded as a function of the incident electron energy at different $\mathrm{Cs}$ coverages allowed to spatially resolve the evolution of the local work function (WF) during the activation process. While the average WF drops by more than 3 eV, the local WF remains quite uniform across the surface throughout the activation process. Maximum fluctuations of less than 0.2 eV were observed in the WF maps for $\mathrm{Cs}$ coverage of a fraction of a monolayer. These fluctuations are mainly related to the surface topography, in particular, to the atomic steps' structure, which replicates the substrate miscut. Apart from these weak spatial fluctuations, no $\mathrm{Cs}$ clusters that would induce strong local WF contrast were observed at the scale of the 20-nm resolution of the measurements. These observations agree with the simple model of semiconductor activation to negative electron affinity that describes the formation of a dipole layer as responsible for the lowering of the WF. Additionally, at complete $\mathrm{Cs}$ coverage, the WF becomes fully homogeneous over the surface, smoothing out features originating from defects and topography.

Physical Review AppliedVol. 22(3)
École Polytechnique (FR), Lawrence Berkeley National Laboratory (US), University of California, Santa Barbara (US)
National Science Foundation, U.S. Department of Energy, Simons Foundation, Agence Nationale de la Recherche, Office of Science, Office of Energy Efficiency and Renewable Energy, University of California, Santa Barbara, Basic Energy Sciences, Solid State Lighting and Energy Electronics Center, University of California Santa Barbara, Office of Energy Efficiency, Core Research for Evolutional Science and Technology
Affordable and clean energy
Openalex Percentile: Top 44%
Photocathodes and Microchannel Plates
0.37
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