Synthesis of Sulfoxides by Palladium-Catalyzed Arylation of Sulfenate Anions with Aryl Thianthrenium Salts
A novel and highly efficient Pd-catalyzed arylation of sulfenate anions with aryl thianthrenium salts is demonstrated. This procedure provides a practical protocol to synthesize various diaryl and alkyl aryl sulfoxides in moderate-to-good yields. The new approach shows mild reaction conditions, broad substrate scope, and good functional group tolerance.
Authors
- Haiyang Fei
- Kun Huang (ORCID: https://orcid.org/0000-0003-2737-1189)
- Chao‐Guo Yan (ORCID: https://orcid.org/0000-0002-2777-9582)
- Ying Han (ORCID: https://orcid.org/0000-0002-2424-5163)
- Qianqian Hu (ORCID: https://orcid.org/0000-0001-5593-8168)
- Lei Wang (ORCID: https://orcid.org/0000-0002-8792-0234)
- Jing Sun (ORCID: https://orcid.org/0009-0007-2335-322X)
- Feifei Jin
- Qiang Wang (ORCID: https://orcid.org/0000-0002-1715-8758)
Institutions
- Jiangsu Food and Pharmaceutical Science College (CN)
- Yangzhou University (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2024-09-03
- DOI
- https://doi.org/10.1021/acs.joc.4c01418
- Citations
- 3
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.75
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Jiangsu Province