Metal‐Free Aminophosphonation: Eco‐Friendly Synthesis and Photophysical Properties of Fluorescent 3‐(Aminoimidazo[1,2‐<i>a</i>]Pyridin‐2‐yl)Phosphonates

Abstract We report a novel, metal‐free procedure for the direct aminophosphonation of imidazo[1,2‐ a ]pyridines in green solvents under open air conditions. This method is characterized by its mild and sustainable conditions, ease of operation, scalability, and excellent functional group compatibility. The synthesized compounds exhibit promising photophysical properties, including significant Stokes shifts and quantum yields, making them potential candidates for innovative fluorescent probes.