Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites

In this study, significant improvements in mechanical properties have been seen through the efficient inclusion of Oil Palm Cellulose Nanofibrils (CNF) as nano-fillers into green polymer matrices produced from biomass with a 28 % carbon content. The goal of the research was to make green epoxy nanocomposites utilizing solution blending process with acetone as the solvent with the different CNF loadings (0.1, 0.25, and 0.5 wt%). An ultrasonic bath was used in conjunction with mechanical stirring to guarantee that CNF was effectively dispersed throughout the green epoxy. The resultant nanocomposites underwent thorough evaluation, comparing them to unfilled green epoxy and evaluating their morphological, mechanical, and thermal behavior using a variety of instruments. Field-emission scanning electron microscopy (FE-SEM) was used to validate findings, which showed that the CNF were dispersed optimally inside the nanocomposites. The thermal degradation temperature (Td) of the nanocomposites showed a marginal decrement of 0.8 % in temperatures (from 348 °C to 345 °C), between unfilled green epoxy (neat) and 0.1 wt% of CNF loading. The mechanical test results, which showed a 13.3 % improvement in hardness and a 6.45 % rise in tensile strength when compared to unfilled green epoxy, were in line with previously published research. Overall, the outcomes showed that green nanocomposites have significantly improved in performance.

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Publication Details

Journal
International Journal of Biological Macromolecules
Published
2024-09-02
DOI
https://doi.org/10.1016/j.ijbiomac.2024.134421
Citations
20
Primary Topic
Advanced Cellulose Research Studies
Type
article
Field-Weighted Citation Impact
3.47

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article

Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites

Mohd Roshdi Hassan, S.M. Sapuan, R.A. Ilyas, Umer Rashid et al.
20 citations
International Journal of Biological Macromolecules
Advanced Cellulose Research Studies
3.47
article

Thermal, mechanical, and morphological properties of oil palm cellulose nanofibril reinforced green epoxy nanocomposites

Mohd Roshdi Hassan, S.M. Sapuan, R.A. Ilyas, Umer Rashid, J. Yusuf
article en
20 citations

Abstract

In this study, significant improvements in mechanical properties have been seen through the efficient inclusion of Oil Palm Cellulose Nanofibrils (CNF) as nano-fillers into green polymer matrices produced from biomass with a 28 % carbon content. The goal of the research was to make green epoxy nanocomposites utilizing solution blending process with acetone as the solvent with the different CNF loadings (0.1, 0.25, and 0.5 wt%). An ultrasonic bath was used in conjunction with mechanical stirring to guarantee that CNF was effectively dispersed throughout the green epoxy. The resultant nanocomposites underwent thorough evaluation, comparing them to unfilled green epoxy and evaluating their morphological, mechanical, and thermal behavior using a variety of instruments. Field-emission scanning electron microscopy (FE-SEM) was used to validate findings, which showed that the CNF were dispersed optimally inside the nanocomposites. The thermal degradation temperature (Td) of the nanocomposites showed a marginal decrement of 0.8 % in temperatures (from 348 °C to 345 °C), between unfilled green epoxy (neat) and 0.1 wt% of CNF loading. The mechanical test results, which showed a 13.3 % improvement in hardness and a 6.45 % rise in tensile strength when compared to unfilled green epoxy, were in line with previously published research. Overall, the outcomes showed that green nanocomposites have significantly improved in performance.

International Journal of Biological MacromoleculesVol. 278(Pt 3)
Universiti Putra Malaysia (MY), Chulalongkorn University (TH), University of Technology Malaysia (MY), Universiti Tenaga Nasional (MY)
Ministry of Higher Education, Malaysia, Universiti Putra Malaysia
Openalex Percentile: Top 7%
Advanced Cellulose Research Studies
3.47
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