Controllable Synthesis of Magnetic Composite Derived from MIL-88D and Study on Adsorption Properties of Cu2+

In this paper, MIL-88D (Fe) with spindle shape was prepared by the hydrothermal synthesis method, a metal oxide with a new structure was obtained by calcination at different temperatures as a precursor, and a magnetic iron oxide composite was prepared successfully. At the same time, it was used as an adsorption material for the adsorption of heavy metal ions Cu2+. The influence of the initial pH value and adsorption time on the adsorption effect was investigated, the adsorption kinetics and adsorption isotherm were further fitted, and the adsorption mechanism was preliminarily analyzed. The results show that the magnetic iron oxide composites have a good adsorption capacity for Cu2+. The pH value is an important parameter that affects the adsorption effect. The adsorption of Cu2+ by magnetic iron oxide composites reached adsorption equilibrium in 30 min. The adsorption of Cu2+ by magnetic iron oxide composites conforms to the second-order reaction kinetics and Langmuir adsorption isotherm equation, which indicates that the adsorption process mainly occurs through chemisorption and typical single-molecular-layer adsorption.

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Publication Details

Journal
Magnetochemistry
Published
2024-08-31
DOI
https://doi.org/10.3390/magnetochemistry10090064
Primary Topic
Adsorption and biosorption for pollutant removal
Type
article
Field-Weighted Citation Impact
0.00

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Controllable Synthesis of Magnetic Composite Derived from MIL-88D and Study on Adsorption Properties of Cu2+

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Magnetochemistry
Adsorption and biosorption for pollutant removal
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Controllable Synthesis of Magnetic Composite Derived from MIL-88D and Study on Adsorption Properties of Cu2+

Min Lu, Zhongyuan Zheng, Jiacheng Zhang, Ling Jiang, Jinshan Yu
article en

Abstract

In this paper, MIL-88D (Fe) with spindle shape was prepared by the hydrothermal synthesis method, a metal oxide with a new structure was obtained by calcination at different temperatures as a precursor, and a magnetic iron oxide composite was prepared successfully. At the same time, it was used as an adsorption material for the adsorption of heavy metal ions Cu2+. The influence of the initial pH value and adsorption time on the adsorption effect was investigated, the adsorption kinetics and adsorption isotherm were further fitted, and the adsorption mechanism was preliminarily analyzed. The results show that the magnetic iron oxide composites have a good adsorption capacity for Cu2+. The pH value is an important parameter that affects the adsorption effect. The adsorption of Cu2+ by magnetic iron oxide composites reached adsorption equilibrium in 30 min. The adsorption of Cu2+ by magnetic iron oxide composites conforms to the second-order reaction kinetics and Langmuir adsorption isotherm equation, which indicates that the adsorption process mainly occurs through chemisorption and typical single-molecular-layer adsorption.

MagnetochemistryVol. 10(9)
Northeast Electric Power University (CN), Tianjin Research Institute of Electric Science (China) (CN)
National Natural Science Foundation of China, People's Government of Jilin Province, Education Department of Jilin Province
Clean water and sanitation
Openalex Percentile: Top 86%
Adsorption and biosorption for pollutant removal
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