Titanium Complex with New Schiff Base 4-(N, N-dimethylaminobenzylidene)-1- phenylsemicarbazide: Synthesis, Thermal, XRD, and Antibacterial properties

4-(N, N-dimethylaminobenzylidene) 1-phenylsemicarbazide Schiff base (SB) was synthesized from 1-phenylsemicarbazide and 4-(N,N-dimethylaminobenzaldehyde). Numerous analytical approaches, such as ele-mental analysis, 1HNMR, 13CNMR, electronic spectra, and FT-IR spectroscopy were utilized to analyze the newly synthesized Schiff base. The Ti (IV) Schiff base complex was produced, and its electrolytic nature, stability, and octahedral structural properties were determined by elemental, IR, UV-Vis spectral, conductivity, and thermal studies (TGA-DTA). From XRD results, the practical size of Schiff base and its complex were in the nano range with crystallinity structure. To evaluate the antibacterial activity, the free ligand and its complex were assessed in vitro against Pseudomonas aeruginosa, Escherichia coli, and Staphylococcus aureus. These results show that the metal complex has stronger antibacterial action than the Schiff base ligand.

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Journal
مجلة جامعة صنعاء للعلوم التطبيقية والتكنولوجيا
Published
2024-08-31
DOI
https://doi.org/10.59628/jast.v2i4.1145
Citations
2
Primary Topic
Organometallic Compounds Synthesis and Characterization
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article
Field-Weighted Citation Impact
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article

Titanium Complex with New Schiff Base 4-(N, N-dimethylaminobenzylidene)-1- phenylsemicarbazide: Synthesis, Thermal, XRD, and Antibacterial properties

Ahmed N. Al‐Hakimi, Yasmin M.S. Jamil, Fathi M. Al-Azab, Nedhal A. A. Al-Selwi et al.
2 citations
مجلة جامعة صنعاء للعلوم التطبيقية والتكنولوجيا
Organometallic Compounds Synthesis and Characterization
0.50
article

Titanium Complex with New Schiff Base 4-(N, N-dimethylaminobenzylidene)-1- phenylsemicarbazide: Synthesis, Thermal, XRD, and Antibacterial properties

Ahmed N. Al‐Hakimi, Yasmin M.S. Jamil, Fathi M. Al-Azab, Nedhal A. A. Al-Selwi, Dheya A. Hameed, Gamil M. S. Qasem, Abuzar Ebead Albadri Albadri
article en
2 citations

Abstract

4-(N, N-dimethylaminobenzylidene) 1-phenylsemicarbazide Schiff base (SB) was synthesized from 1-phenylsemicarbazide and 4-(N,N-dimethylaminobenzaldehyde). Numerous analytical approaches, such as ele-mental analysis, 1HNMR, 13CNMR, electronic spectra, and FT-IR spectroscopy were utilized to analyze the newly synthesized Schiff base. The Ti (IV) Schiff base complex was produced, and its electrolytic nature, stability, and octahedral structural properties were determined by elemental, IR, UV-Vis spectral, conductivity, and thermal studies (TGA-DTA). From XRD results, the practical size of Schiff base and its complex were in the nano range with crystallinity structure. To evaluate the antibacterial activity, the free ligand and its complex were assessed in vitro against Pseudomonas aeruginosa, Escherichia coli, and Staphylococcus aureus. These results show that the metal complex has stronger antibacterial action than the Schiff base ligand.

مجلة جامعة صنعاء للعلوم التطبيقية والتكنولوجياVol. 2(4)
Qassim University (SA), Sana'a University (YE), Ibb University (YE)
Clean water and sanitation
Openalex Percentile: Top 40%
Organometallic Compounds Synthesis and Characterization
0.50
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