Crystal structure and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromophenyl)-1,2,3,4-tetrahydroquinolin-4-yl]pyrrolidin-2-one
This study presents the synthesis, characterization and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromo-phen-yl)-1,2,3,4-tetra-hydro-quinolin-4-yl]pyrrolidin-2-one, C<sub>19</sub>H<sub>18</sub>Br<sub>2</sub>N<sub>2</sub>O. In the title compound, the pyrrolidine ring adopts a distorted envelope configuration. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O, C-H⋯O and C-H⋯Br hydrogen bonds, forming a three-dimensional network. In addition, pairs of mol-ecules along the <i>c</i> axis are connected by C-H⋯π inter-actions. According to a Hirshfeld surface study, H⋯H (36.9%), Br⋯H/H⋯Br (28.2%) and C⋯H/H⋯C (24.3%) inter-actions are the most significant contributors to the crystal packing.
Authors
- Nurlana D. Sadikhova
- Ajaya Bhattarai (ORCID: https://orcid.org/0000-0002-2648-4686)
- Mikhail S. Grigoriev (ORCID: https://orcid.org/0000-0002-6363-5535)
- Khudayar I. Hasanov
- Anastasia A. Pronina
- Mehmet Akkurt (ORCID: https://orcid.org/0000-0003-2421-0929)
- Tahir A. Javadzade (ORCID: https://orcid.org/0000-0003-3327-4430)
- Alexandra G. Kutasevich
Institutions
- Khazar University (AZ)
- Peoples' Friendship University of Russia (RU)
- Tribhuvan University (NP)
- Azerbaijan Medical University (AZ)
- Baku State University (AZ)
- Russian New University (RU)
- Western Caspian University (AZ)
- Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (RU)
- Erciyes University (TR)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2024-08-30
- DOI
- https://doi.org/10.1107/s2056989024008144
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Baki Dövlət Universiteti
- RUDN University