Enhancing the potential application of food-waste biochar as a sustainable bio-solid fuel: Analysis of post-treatment and combustion behavior

Food-waste biochar holds significant potential as a bio-solid fuel for achieving carbon neutrality; however, its high content of sodium (Na), potassium (K), calcium (Ca), chlorine (Cl), and nitrogen, inhibits its potential use. This study explored the effects of post-treatment with ascorbic, acetic, citric, and iminodiacetic acids on the properties of food-waste biochar and volatile ionic substances to establish a foundation for assessing both the environmental impact and practical use of food waste. Post-treatment with organic acids achieved 92% Cl-removal efficiency and induced deformation of the functional groups of food-waste biochar surfaces, leading to the re-adsorption of alkali and alkaline earth metals. This re-adsorption of alkali metal ions showed a distinct correlation with NO_x mitigation. The amount of re-adsorbed Na and K varied based on the types of organic acids, resulting in different NO_x emission reduction effects. Iminodiacetic acid was particularly effective in alleviating Ca and PO₄ volatilization, whereas citric acid exhibited the highest Ca elution performance, and the Ca-contained leachate is a potential source of CO₂ storage through indirect mineral carbonation. Acetic acid is the most feasible alternative, considering both economic and environmental aspects. The findings suggest that the post-treatment of food-waste biochar effectively mitigates air pollutants during combustion and is beneficial for sustainable biosolid fuel production and bio-waste management.