Universal Time and Length Scales of Polar Active Polymer Melts

We present an in-depth multiscale analysis of the conformations and dynamics of polar active polymers, comparing very dilute and very dense conditions. We unveil characteristic length and time scales, common to both dilute and dense systems, that recapitulate the conformational and dynamical properties of these active polymers upon varying both the polymer size and the strength of the activity. Specifically, we find that a correlation (or looping) length characterizes the polymer conformations and the monomer dynamics. Instead, the dynamics of the center of mass can be fully characterized by the end-to-end mean-square distance and by the associated relaxation time. As such, we show that the dynamics of individual chains in melts of polar active polymers is not controlled by entanglements, but only by the strength of the self-propulsion.

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Publication Details

Journal
ACS Macro Letters
Published
2024-08-30
DOI
https://doi.org/10.1021/acsmacrolett.4c00423
Citations
9
Primary Topic
Micro and Nano Robotics
Type
article
Field-Weighted Citation Impact
2.80

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article

Universal Time and Length Scales of Polar Active Polymer Melts

Angelo Rosa, Emanuele Locatelli, Mattia Alberto Ubertini
9 citations
ACS Macro Letters
Micro and Nano Robotics
2.80
article

Universal Time and Length Scales of Polar Active Polymer Melts

Angelo Rosa, Emanuele Locatelli, Mattia Alberto Ubertini
article en
9 citations

Abstract

We present an in-depth multiscale analysis of the conformations and dynamics of polar active polymers, comparing very dilute and very dense conditions. We unveil characteristic length and time scales, common to both dilute and dense systems, that recapitulate the conformational and dynamical properties of these active polymers upon varying both the polymer size and the strength of the activity. Specifically, we find that a correlation (or looping) length characterizes the polymer conformations and the monomer dynamics. Instead, the dynamics of the center of mass can be fully characterized by the end-to-end mean-square distance and by the associated relaxation time. As such, we show that the dynamics of individual chains in melts of polar active polymers is not controlled by entanglements, but only by the strength of the self-propulsion.

ACS Macro LettersVol. 13(9)
Scuola Internazionale Superiore di Studi Avanzati (IT), Istituto Nazionale di Fisica Nucleare, Sezione di Padova (IT)
European Commission, European Cooperation in Science and Technology, Ministero dell’Istruzione, dell’Università e della Ricerca
Openalex Percentile: Top 8%
Micro and Nano Robotics
2.80
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Universal Time and Length Scales of Polar Active Polymer Melts — Angelo Rosa, Emanuele Locatelli, et al. · ACS Macro Letters (2024) | TGRS Research Map | TGRS