Acid‐Promoted Self‐Photocatalyzed Regioselective Oxidation: A Novel Strategy for Accessing Quinoxaline‐2,3‐diones

Disclosed here is an efficient approach for the preparation of quinoxaline-2,3-diones using air (O<sub>2</sub>) as a green oxidant via acid-promoted self-photocatalyzed regioselective oxidation of quinoxalin-2(1H)-ones at C-3 position. This protocol presents a novel synthetic route for the preparation of quinoxaline-2,3-dione derivatives, featuring mild reaction conditions, simple operation, and a wide range of substrates, without the need for external photocatalysts, metal reagents, and strong oxidants.

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Publication Details

Journal
Chemistry - A European Journal
Published
2024-08-29
DOI
https://doi.org/10.1002/chem.202402848
Citations
6
Primary Topic
Synthesis and Biological Evaluation
Type
article
Field-Weighted Citation Impact
1.50

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article

Acid‐Promoted Self‐Photocatalyzed Regioselective Oxidation: A Novel Strategy for Accessing Quinoxaline‐2,3‐diones

Shengjie Song, Jianjun Li, Jie Sun, Lijun Zheng et al.
6 citations
Chemistry - A European Journal
Synthesis and Biological Evaluation
1.50
article

Acid‐Promoted Self‐Photocatalyzed Regioselective Oxidation: A Novel Strategy for Accessing Quinoxaline‐2,3‐diones

Shengjie Song, Jianjun Li, Jie Sun, Lijun Zheng, Xiaoqing Peng, Binjie Zhou, Zhi Chen
article en
6 citations

Abstract

Disclosed here is an efficient approach for the preparation of quinoxaline-2,3-diones using air (O<sub>2</sub>) as a green oxidant via acid-promoted self-photocatalyzed regioselective oxidation of quinoxalin-2(1H)-ones at C-3 position. This protocol presents a novel synthetic route for the preparation of quinoxaline-2,3-dione derivatives, featuring mild reaction conditions, simple operation, and a wide range of substrates, without the need for external photocatalysts, metal reagents, and strong oxidants.

Chemistry - A European JournalVol. 30(68)
Zhejiang University of Technology (CN)
National Natural Science Foundation of China
Clean water and sanitation
Openalex Percentile: Top 19%
Synthesis and Biological Evaluation
1.50
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