Visible Light Mediated Difluoroalkylation of Alkenes Using Mercaptobenzothiazole‐Derived Sulfide Reagent
Abstract A method for the reductive difluoromethylation of alkenes with 2‐difluoromethylthio(benzothiazole) under photocatalytic conditions is described. The reaction involves the generation of the difluoromethyl radical by means of trimethyltriazinane, which serves as a precursor for the strongly reducing cyclic diaminoalkyl radical.
Authors
- Vitalij V. Levin (ORCID: https://orcid.org/0000-0002-5606-8085)
- Alexander D. Dilman (ORCID: https://orcid.org/0000-0001-8048-7223)
- Artem O. Sorokin
Institutions
- Lomonosov Moscow State University (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
Publication Details
- Journal
- Advanced Synthesis & Catalysis
- Published
- 2024-08-29
- DOI
- https://doi.org/10.1002/adsc.202400884
- Citations
- 1
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.21
Funders
- Russian Science Foundation