A Novel Concept of Nano-Enhanced Phase Change Material

In the actual context of growing concerns over sustainability and energy efficiency, Phase Change Materials (PCMs) have gained attention as promising solutions for enhancing energy storage and release efficiency. On another hand, materials based on graphene oxide (GO) have proven antibacterial activity, biocompatibility, efficiency in microbial growth inhibition, and pollutant removal. Integrating nanoparticles into PCMs and creating Nano-Enhanced Phase Change Materials (NEPCMs) have opened new horizons for optimizing the performance of these systems and sustainable development. The key objective of this work is to gain insight into NECPMs, which are used in solar wall systems to enhance solar energy storage. Paraffin RT31 was mixed with Cu nanoparticles, graphene oxide (GO), and Cu-decorated GO (Cu@GO) at loading ratios ranging from 1% to 4% (<i>w</i>/<i>w</i> nanoparticles with respect to RT31). The compositions were characterized through Differential Scanning Calorimetry (DSC) and rheology tests. The decoration of the carbon-based nanoparticles was performed using the ultrasonication procedure, and the decoration efficiency was confirmed through X-ray Photoelectron Spectroscopy (XPS). The rheologic measurements were performed to correlate the flow behavior of the NEPCM with their composition at various temperatures. The study methodically investigated these composites' latent heat values, phase change peak temperatures, and solidification phase change temperatures. Compared to pure paraffin, the solidification of the formulations obtained using Cu@GO exhibits the largest increase in latent heat, with a 12.07% growth at a concentration of 2%. Additionally, at a 4% concentration of NEPCM, the largest increase in thermal conductivity was attained, namely 12.5%.