Photoresponsive Dioxazaborocanes‐Containing Oligomers
The synthetic methodology for the preparation of photoresponsive dioxazaborocanes-containing oligomers is developed. It relies on the transformation of the (diisopropylamino)boryl group (-BH(NiPr<sub>2</sub>)) into a dioxazaborocane unit in the presence of β-aminodiols and involves a bis-borylated dithienylethene photochromic unit. The photophysical properties of the obtained oligomers are evaluated as well as their processability for the preparation of spin-coated films. The photomechanical behavior of the resulting films is assessed via displacement tracking profile.
Authors
- Gilles Alcaraz (ORCID: https://orcid.org/0000-0001-8705-5917)
- Stéphane Aloïse (ORCID: https://orcid.org/0000-0003-1894-8775)
- Nour Nour Eddine
- Marie Cordier≈ (ORCID: https://orcid.org/0000-0003-0917-2725)
- Marc Devillard (ORCID: https://orcid.org/0000-0002-3821-0885)
- Ismael Arroyo Diaz (ORCID: https://orcid.org/0009-0000-3844-5724)
- Laurine Meslong
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université de Lille (FR)
- Institut des Sciences Chimiques de Rennes (FR)
- Laboratoire de Spectroscopie pour les Interactions, la Réactivité et l'Environnement (FR)
- Université de Rennes (FR)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2024-08-29
- DOI
- https://doi.org/10.1002/chem.202402912
- Primary Topic
- Photochromic and Fluorescence Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Agence Nationale de la Recherche