Formulation Development of Dial-A-Drive PETN-Based Explosives

Hot-spot mechanisms at the grain-scale play an important role in explosive behavior, especially in shock initiation sensitivity, and detonation properties coupled to shock-initiability.To better understand how dilution of energetic concentration affects communication between hot-spots, and thus its performance, we investigated the detonation properties of dilute plastic bonded explosives (PBX) comprised of 20-60 wt.% PETN in a silicone-based polymeric binder.With the intention of probing low performance in dilute PBX formulations, we attempted to get a formulation with a P CJ as low as 3 GPa and a D vel of 3 mm/s as well as cast densities within 3% of the theoretical maximum density to ensure consistent void-volume control.

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OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)
Published
2024-08-16
Primary Topic
Energetic Materials and Combustion
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article

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article

Formulation Development of Dial-A-Drive PETN-Based Explosives

Candace M. Landeros
OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)
Energetic Materials and Combustion
article

Formulation Development of Dial-A-Drive PETN-Based Explosives

Candace M. Landeros
article en

Abstract

Hot-spot mechanisms at the grain-scale play an important role in explosive behavior, especially in shock initiation sensitivity, and detonation properties coupled to shock-initiability.To better understand how dilution of energetic concentration affects communication between hot-spots, and thus its performance, we investigated the detonation properties of dilute plastic bonded explosives (PBX) comprised of 20-60 wt.% PETN in a silicone-based polymeric binder.With the intention of probing low performance in dilute PBX formulations, we attempted to get a formulation with a P CJ as low as 3 GPa and a D vel of 3 mm/s as well as cast densities within 3% of the theoretical maximum density to ensure consistent void-volume control.

OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)
Lawrence Livermore National Laboratory (US)
U.S. Department of Energy, National Nuclear Security Administration, Lawrence Livermore National Laboratory
Energetic Materials and Combustion
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