Synthesis and EPR Studies of Zinc and Copper Tris(2‐pyridylmethyl)amines (TPMA) Metal Complexes Containing TEMPO Functionalities
Abstract A new family of stable radical‐containing polytopic ligands based on tris(2‐pyridylmethyl)amines TPMA architecture and their corresponding metal complexes have been synthesized. These molecular systems offered the possibility to investigate how various spin carriers, such as the metal ion and the organic radical, influence their EPR properties mainly through the empirical ratio of peak heights d 1 /d . Moreover, it has been possible to analyze how different conformations of TEMPO radical units in the molecular skeleton affect the metallic system.
Authors
- Elena Badetti (ORCID: https://orcid.org/0000-0002-3984-7829)
- J. Vidal-Gancedo
- Vega Lloveras (ORCID: https://orcid.org/0000-0002-9653-3340)
- Cristiano Zonta (ORCID: https://orcid.org/0000-0003-1749-7482)
- Jaume Veciana (ORCID: https://orcid.org/0000-0003-1023-9923)
- Giulia Licini (ORCID: https://orcid.org/0000-0001-8304-0443)
- Francesca A. Scaramuzzo (ORCID: https://orcid.org/0000-0001-9921-5252)
- Melvin Raulin (ORCID: https://orcid.org/0000-0003-2460-2607)
Institutions
- University of Padua (IT)
- Ca' Foscari University of Venice (IT)
- Instituto de Salud Carlos III (ES)
- Material (Belgium) (BE)
- Institut de Ciència de Materials de Barcelona (ES)
- Sapienza University of Rome (IT)
Publication Details
- Journal
- European Journal of Organic Chemistry
- Published
- 2024-08-20
- DOI
- https://doi.org/10.1002/ejoc.202400384
- Primary Topic
- Metal complexes synthesis and properties
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Fondazione Cassa di Risparmio di Padova e Rovigo
- Generalitat de Catalunya
- Università degli Studi di Padova
- Ministerio de Ciencia e Innovación
- Centro de Investigación Biomédica en Red en Bioingeniería, Biomateriales y Nanomedicina