From perfluoroalkyl aryl sulfoxides to <i>ortho</i> thioethers
Access to original <i>ortho</i> thioether derivatives was achieved through a [3,3]-rearrangement in a one-pot two-step protocol. Several aryl-SCF<sub>3</sub> compounds are reported by variation of the nitrile or of the trifluoroalkyl sulfoxide starting material. The variation of the perfluoroalkyl chain was also possible.
Authors
- Guillaume Dagousset (ORCID: https://orcid.org/0000-0001-8720-3828)
- Bruce Pégot (ORCID: https://orcid.org/0000-0001-5137-5548)
- Yang Li (ORCID: https://orcid.org/0000-0002-8494-1873)
- Emmanuel Magnier (ORCID: https://orcid.org/0000-0003-3392-3971)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université de Versailles Saint-Quentin-en-Yvelines (FR)
- Université Paris-Saclay (FR)
- Institut Lavoisier de Versailles (FR)
Publication Details
- Journal
- Beilstein Journal of Organic Chemistry
- Published
- 2024-08-23
- DOI
- https://doi.org/10.3762/bjoc.20.181
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Centre National de la Recherche Scientifique