Nucleating agent for polypropylene comprising the calcium salt of 4‐methyl‐cyclohexane‐1,2‐dicarboxylic acid

Abstract In the present study, a novel crystalline nucleating agent for isotactic polypropylene (PP) comprising the calcium salt of 4‐methyl‐cyclohexane‐1,2‐dicarboxylic acid (MHPA‐Ca) is developed. The performance of the nucleating agent is evaluated by determining the crystallization temperature and isothermal crystallization period of the PP by differential scanning calorimetry, and comparing them with those obtained using the calcium salt of cyclohexane‐1,2‐dicarboxylic acid (HHPA‐Ca), which is one of the most effective nucleating agents for PP. The results demonstrate that the nucleating ability of MHPA‐Ca is much stronger than that of HHPA‐Ca. Consequently, an injection‐molded plate containing MHPA‐Ca has a high degree of chain orientation.

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Publication Details

Journal
Journal of Applied Polymer Science
Published
2024-08-26
DOI
https://doi.org/10.1002/app.56201
Citations
2
Primary Topic
Polymer crystallization and properties
Type
article
Field-Weighted Citation Impact
0.34
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article

Nucleating agent for polypropylene comprising the calcium salt of 4‐methyl‐cyclohexane‐1,2‐dicarboxylic acid

Kazuya Matsumoto, Masayuki Yamaguchi, Mitsuko Inoue, Takahiro Inoue et al.
2 citations
Journal of Applied Polymer Science
Polymer crystallization and properties
0.34
article

Nucleating agent for polypropylene comprising the calcium salt of 4‐methyl‐cyclohexane‐1,2‐dicarboxylic acid

Kazuya Matsumoto, Masayuki Yamaguchi, Mitsuko Inoue, Takahiro Inoue, Shohei Iwasaki
article en
2 citations

Abstract

Abstract In the present study, a novel crystalline nucleating agent for isotactic polypropylene (PP) comprising the calcium salt of 4‐methyl‐cyclohexane‐1,2‐dicarboxylic acid (MHPA‐Ca) is developed. The performance of the nucleating agent is evaluated by determining the crystallization temperature and isothermal crystallization period of the PP by differential scanning calorimetry, and comparing them with those obtained using the calcium salt of cyclohexane‐1,2‐dicarboxylic acid (HHPA‐Ca), which is one of the most effective nucleating agents for PP. The results demonstrate that the nucleating ability of MHPA‐Ca is much stronger than that of HHPA‐Ca. Consequently, an injection‐molded plate containing MHPA‐Ca has a high degree of chain orientation.

Journal of Applied Polymer ScienceVol. 141(45)
Japan Advanced Institute of Science and Technology (JP), New Japan Chemical (Japan) (JP)
Clean water and sanitation
Openalex Percentile: Top 50%
Polymer crystallization and properties
0.34
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