Optimization of mission enabling broadband Lyman ultraviolet series to infrared aluminum lithium fluoride reflectors

The Habitable Worlds Observatory (HWO) concept NASA flagship mission aims extend the ultraviolet (UV) observation range and sensitivity capabilities of the Hubble Space Telescope (HST) with respective goals of reaching photons down to 100 nm and containing an ultraviolet multi-object spectrograph with sensitivity improved 30-100 times. Adding the sensitivity capabilities near the Lyman series spectral range of ~100-121.6 nm reduces the reliance of redshift for key diagnostic ion lines such as O VI (103.2 nm), and heavily ionized gases of Ne VIII (77.5 nm) and MgX (62.5 nm). Clean and unoxidized aluminum (Al) reflectors provide optimal efficiency over a broadband down to the extreme ultraviolet (EUV) wavelength of ~83 nm. To prevent oxidation and maintain high spectral efficiency down to ~100 nm, the Al reflector is conventionally overcoated with a thin lithium fluoride (LiF) layer. We investigate the optimization of the deposition of the Al+LiF coating material composition to attain high spectral efficiency broadband reflectors down to 100 nm and enable the scientific goals of HWO. Lithium hexafluoroaluminate (Li₃AlF₆) is investigated as a different composition form of LiF to overcoat Al. The spectral efficiency and durability of the reflectors is evaluated. We will demonstrate the use of Li₃AlF₆ as an overcoat to protect aluminum yields ultra-high efficiency at the Hydrogen Lyman-alpha (HLyα, 121.6 nm) line with experimental reflectance values peaking up to 99%.