Highly Stable Subnanometric PtIn Clusters for the Selective Dehydrogenation of Alkanes
Subnanometric PtIn clusters have been synthesized within pure silica MFI zeolites by post-synthetic incorporation of In to Pt@K-MFI. The optimized PtIn@K-MFI catalyst outcompetes state-of-the-art PtSn formulations in ethane and propane dehydrogenations, avoiding the need of large excess of Pt promoters and harsh reductive conditions.
Authors
- Avelino Corma (ORCID: https://orcid.org/0000-0002-2232-3527)
- Chengeng Li (ORCID: https://orcid.org/0000-0003-2004-5081)
- Sara Yacob (ORCID: https://orcid.org/0000-0002-1116-8883)
- Miguel López‐Haro (ORCID: https://orcid.org/0000-0003-2560-8015)
- Randall J. Meyer (ORCID: https://orcid.org/0000-0002-0679-0029)
- Manuel Moliner (ORCID: https://orcid.org/0000-0002-5440-716X)
- José J. Calvino (ORCID: https://orcid.org/0000-0002-0989-1335)
- Pedro Serna (ORCID: https://orcid.org/0000-0002-5597-1934)
- Elaine Gomez (ORCID: https://orcid.org/0000-0003-1991-0488)
Institutions
- Consejo Superior de Investigaciones Científicas (ES)
- Universidad de Cádiz (ES)
- Instituto de Tecnología Química (ES)
- Universitat Politècnica de València (ES)
- Beijing University of Chemical Technology (CN)
- ExxonMobil (United States) (US)
Publication Details
- Journal
- ChemSusChem
- Published
- 2024-08-26
- DOI
- https://doi.org/10.1002/cssc.202401284
- Citations
- 7
- Primary Topic
- Catalysis and Oxidation Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.75
Funders
- U.S. Department of Energy
- Ministerio de Ciencia, Innovación y Universidades
- Generalitat Valenciana
- Ministerio de Ciencia e Innovación
- Office of Science
- ExxonMobil Research and Engineering Company
- European Regional Development Fund
- Agencia Estatal de Investigación
- Brookhaven National Laboratory