A General Synthesis of 3,7-Di(carboxyalkyl)-Functionalized Pyrimidopteridine Photoredox Catalysts
Abstract In this work, the multi-step synthesis of three novel pyrimidopteridine photoredox catalysts is reported. These catalysts contain di(carboxyalkyl)-substitution at the 3- and 7-positions as handles for further synthetic modifications. The catalysts are fully characterized including by photochemical and electrochemical means. Additionally, a catalytic application in the oxidative annulation of 2-phenylbenzoic acid is presented.
Authors
- Ayla Kruse (ORCID: https://orcid.org/0000-0002-2858-8462)
- Tobias Taeufer (ORCID: https://orcid.org/0000-0002-1214-7283)
- Stefan Lochbrunner (ORCID: https://orcid.org/0000-0001-9729-8277)
- Jola Pospech (ORCID: https://orcid.org/0000-0001-7794-2600)
- Johannes Fessler (ORCID: https://orcid.org/0000-0003-2395-8572)
- Sina Brandt
- Dao Xuan Huy
Institutions
- Leibniz Institute for Catalysis (DE)
- FZU ‒ Institute of Physics of the Academy of Sciences of the Czech Republic (CZ)
- University of Rostock (DE)
- Hanoi University of Science and Technology (VN)
Publication Details
- Journal
- Synthesis
- Published
- 2024-08-26
- DOI
- https://doi.org/10.1055/a-2403-2247
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Deutsche Forschungsgemeinschaft