An Analysis of the Spatiotemporal Variability of Key Water Quality Parameters in China

Intensifying anthropogenic disturbances have caused water pollution in China in recent decades. China has a vast territory with diverse climate conditions, land use types, and human activities, leading to significant water quality variability. However, few studies have investigated nationwide spatiotemporal patterns of key water quality parameters. In this study, we analyze monthly water quality observations from 3647 gauge stations to understand how water quality changes over time and space in China. We group the stations by water resource regions and adopt Python and SPSS to analyze the spatiotemporal variability and intercorrelations of eight water quality parameters. Results indicate that the concentrations of biochemical oxygen demand of 5 days (BOD5), chemical oxygen demand (COD), dissolved oxygen (DO), ammonia nitrogen (NH3-N), total nitrogen (TN), and total phosphorus (TP) show similar spatial patterns, with higher concentrations in the northern parts than the southern regions of China. The concentrations of COD and TP are higher in the rainy season than in the dry season, while DO, NH3-N, and TN show the opposite seasonal patterns. Strong positive correlations were found between BOD and COD, NH3-N and TP. The annual cumulative distribution figures demonstrate that all parameters showed slightly lower concentrations in 2022 and 2023 than in 2021, except for DO and TN. The TN/TP ratios across different water resource regions in China are significantly higher than 16, indicating that phosphorus is the limiting factor of eutrophication. This investigation provides a comprehensive understanding of the spatiotemporal variability of water quality parameters across China. The results of this study are highly valuable for investigating mechanisms regulating water quality across large spatial scales, thus providing valuable implications for improving water quality and mitigating water pollution.