The Chemistry of Metal–Organic Frameworks for Multicomponent Gas Separation

Abstract Adsorbents‐based gas separation technologies are regarded as the potential energy‐efficient alternatives towards current thermal‐driven methods, and the study on multi‐component gas separation is essential to deepen our understanding of the adsorbents for practical use. Relative to the ideal two‐component mixtures, both the adsorption behavior and separation mechanisms are obviously more complex in multiple gas mixtures due to their close or even overlapped sizes and properties. The emergence of metal–organic frameworks with controllable pore size and pore chemistry provides the platform for the tailor‐made pore structure to satisfy the harsh requirements of multi‐component gas separation. This minireview highlights the recent advance of multi‐component gas separation using metal–organic frameworks, including multiple impurities removal and selective molecular capture. Combining with the typical cases of hydrocarbon separations (C2, C4, and C8), the detailed discussion about the developed strategies (e.g. self‐adaptive binding sites, multiple binding spaces, synergistic binding sites, synergistic sorbent separation technology, gate‐opening effect, size and thermodynamic combine effect) that are adaptive to different scenarios would be provided. The review will conclude with our perspective on the existing barriers and the future direction of this topic.