Di- and Octanuclear 1,2-Dimethylpyridinium and 3-Bromo-1-Ethylpyridinium Iodoantimonates(III): Crystal Structure and Physicochemical Properties
New antimony complexes, (3-Br-1-EtPy)3[Sb2I9] (1) and (1,2-Me2Py)4[Sb8I28] (2) have been prepared by the reaction of SbI3 with iodides of the corresponding cations in organic solvents. The features of the crystal structure of the compounds have been determined by X-ray diffraction. The complexes are thermally stable at least up to 200°C and have a band gap of ~2.2 eV.
Authors
- Maksim Sokolov (ORCID: https://orcid.org/0000-0001-5244-6301)
- Sergey A. Adonin (ORCID: https://orcid.org/0000-0002-9889-5273)
- Irina A. Shentseva
- Vladimir R. Shayapov (ORCID: https://orcid.org/0000-0001-7647-7743)
- Andrey N. Usoltsev (ORCID: https://orcid.org/0000-0003-3980-5028)
- Nikita A. Korobeynikov (ORCID: https://orcid.org/0000-0003-3399-5975)
- K. A. Tagiltsev
Institutions
- Novosibirsk State University (RU)
- A.E. Favorsky Irkutsk Institute of Chemistry (RU)
- Nikolaev Institute of Inorganic Chemistry (RU)
Publication Details
- Journal
- Russian Journal of Inorganic Chemistry
- Published
- 2024-08-01
- DOI
- https://doi.org/10.1134/s0036023624601156
- Citations
- 1
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.16