Synthesis, Crystal Structure, and Magnetic Properties of Y3–xCex(Fe0.5Ga0.5)5O12 (х = 0, 0.5)

The specific magnetization and magnetic susceptibility of ferrogarnets of the composition Y3–xCex(Fe0.5Ga0.5)5O12 (x = 0; 0.5) obtained by the gel combustion method have been measured. It has been found that after synthesis and subsequent crystallization at pressure ≈ 10–2 Pa at 1023 K for 2 h, the temperature of magnetic phase transformation in the studied compositions Y3–xCex(Fe0.5Ga0.5)5O12 increases with the replacement of yttrium ions Y3+ by Ce3+. In this case, the effective Curie–Weiss temperature Ɵeff of the antiferromagnetic component of exchange magnetic interactions in Y2.5Сe0.5Fe2.5Ga0.5O12 varies from |–570| to |–650| K.

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Publication Details

Journal
Russian Journal of Inorganic Chemistry
Published
2024-08-01
DOI
https://doi.org/10.1134/s0036023624601041
Citations
3
Primary Topic
Magneto-Optical Properties and Applications
Type
article
Field-Weighted Citation Impact
0.63
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article

Synthesis, Crystal Structure, and Magnetic Properties of Y3–xCex(Fe0.5Ga0.5)5O12 (х = 0, 0.5)

Г. Е. Никифорова, K. I. Yanushkevich, М. Н. Смирнова, Е. S. Romanova et al.
3 citations
Russian Journal of Inorganic Chemistry
Magneto-Optical Properties and Applications
0.63
article

Synthesis, Crystal Structure, and Magnetic Properties of Y3–xCex(Fe0.5Ga0.5)5O12 (х = 0, 0.5)

Г. Е. Никифорова, K. I. Yanushkevich, М. Н. Смирнова, Е. S. Romanova, В. А. Кецко
article en
3 citations

Abstract

The specific magnetization and magnetic susceptibility of ferrogarnets of the composition Y3–xCex(Fe0.5Ga0.5)5O12 (x = 0; 0.5) obtained by the gel combustion method have been measured. It has been found that after synthesis and subsequent crystallization at pressure ≈ 10–2 Pa at 1023 K for 2 h, the temperature of magnetic phase transformation in the studied compositions Y3–xCex(Fe0.5Ga0.5)5O12 increases with the replacement of yttrium ions Y3+ by Ce3+. In this case, the effective Curie–Weiss temperature Ɵeff of the antiferromagnetic component of exchange magnetic interactions in Y2.5Сe0.5Fe2.5Ga0.5O12 varies from |–570| to |–650| K.

Russian Journal of Inorganic ChemistryVol. 69(8)
National Academy of Sciences of Belarus (BY), NS Kurnakova Institute of General and Inorganic Chemistry (RU)
Openalex Percentile: Top 32%
Magneto-Optical Properties and Applications
0.63
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