Silver recovery into lead bullion from a lead concentrate by direct reduction with Na ₂ CO ₃ and SiC reagents

Silver has been recovered in lead bullion from a lead concentrate throughout a direct reduction process. The lead concentrate was obtained from a plant that processes polymetallic minerals located in the central mining area of Mexico. The direct reduction process has been tested through mixtures of Na2CO3 and SiC that were put in contact with the lead concentrate at 1000 °C for 60 min to produce lead bullion containing silver and slag. The produced lead bullion containing silver and the slag after direct reduction trials showed that it is possible to recover about 90% of lead and 86.5% of silver into the lead bullion, leading to a low silver content in the slag phase (<0.2 wt.%). The slag was constituted mainly by sodium silicate compounds such as Na2SiO3, Na4SiO4, and Na2Si2O5, when 50 wt. % of Na2CO3 and 10 wt. % of SiC regarding the initial charge of the lead concentrate was used. The proposed process has been assisted thermodynamically by the software FactSage 7.6, which allowed us to predict the main expected compounds and understand the process mechanism for silver recovery into a lead bullion using Na2CO3 and SiC reagents.