Coordination structure and intermolecular interactions in copper(II) acetate complexes with 1,10-phenanthroline and 2,2′-bipyridine

The crystal structures of two coordination compounds, (acetato-κO)(2,2'-bipyridine-κ<sup>2</sup>N,N')(1,10-phenanthroline-κ<sup>2</sup>N,N')copper(II) acetate hexahydrate, [Cu(C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)(C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>)](C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)·6H<sub>2</sub>O or [Cu(bipy)(phen)Ac]Ac·6H<sub>2</sub>O, and (acetato-κO)bis(2,2'-bipyridine-κ<sup>2</sup>N,N')copper(II) acetate-acetic acid-water (1/1/3), [Cu(C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)<sub>2</sub>](C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)·C<sub>2</sub>H<sub>4</sub>O<sub>2</sub>·3H<sub>2</sub>O or [Cu(bipy)<sub>2</sub>Ac]Ac·HAc·3H<sub>2</sub>O, are reported and compared with the previously published structure of [Cu(phen)<sub>2</sub>Ac]Ac·7H<sub>2</sub>O (phen is 1,10-phenanthroline, bipy for 2,2'-bipyridine, ac is acetate and Hac is acetic acid). The geometry around the metal centre is pentacoordinated, but highly distorted in all three cases. The coordination number and the geometric distortion are both discussed in detail, and all complexes belong to the space group P-1. The analysis of the geometric parameters and the Hirshfeld surface properties d<sub>norm</sub> and curvedness provide information about the metal-ligand interactions in these complexes and allow comparison with similar systems.

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Journal
Acta Crystallographica Section C Structural Chemistry
Published
2024-08-23
DOI
https://doi.org/10.1107/s2053229624007617
Citations
1
Primary Topic
Crystal structures of chemical compounds
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article
Field-Weighted Citation Impact
0.16

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article

Coordination structure and intermolecular interactions in copper(II) acetate complexes with 1,10-phenanthroline and 2,2′-bipyridine

Leonardo H. R. Dos Santos, Bernardo L. Rodrigues, Samuel P. Guimaraes
1 citations
Acta Crystallographica Section C Structural Chemistry
Crystal structures of chemical compounds
0.16
article

Coordination structure and intermolecular interactions in copper(II) acetate complexes with 1,10-phenanthroline and 2,2′-bipyridine

Leonardo H. R. Dos Santos, Bernardo L. Rodrigues, Samuel P. Guimaraes
article en
1 citations

Abstract

The crystal structures of two coordination compounds, (acetato-κO)(2,2'-bipyridine-κ<sup>2</sup>N,N')(1,10-phenanthroline-κ<sup>2</sup>N,N')copper(II) acetate hexahydrate, [Cu(C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)(C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>)](C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)·6H<sub>2</sub>O or [Cu(bipy)(phen)Ac]Ac·6H<sub>2</sub>O, and (acetato-κO)bis(2,2'-bipyridine-κ<sup>2</sup>N,N')copper(II) acetate-acetic acid-water (1/1/3), [Cu(C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)(C<sub>10</sub>H<sub>8</sub>N<sub>2</sub>)<sub>2</sub>](C<sub>2</sub>H<sub>3</sub>O<sub>2</sub>)·C<sub>2</sub>H<sub>4</sub>O<sub>2</sub>·3H<sub>2</sub>O or [Cu(bipy)<sub>2</sub>Ac]Ac·HAc·3H<sub>2</sub>O, are reported and compared with the previously published structure of [Cu(phen)<sub>2</sub>Ac]Ac·7H<sub>2</sub>O (phen is 1,10-phenanthroline, bipy for 2,2'-bipyridine, ac is acetate and Hac is acetic acid). The geometry around the metal centre is pentacoordinated, but highly distorted in all three cases. The coordination number and the geometric distortion are both discussed in detail, and all complexes belong to the space group P-1. The analysis of the geometric parameters and the Hirshfeld surface properties d<sub>norm</sub> and curvedness provide information about the metal-ligand interactions in these complexes and allow comparison with similar systems.

Acta Crystallographica Section C Structural ChemistryVol. 80(9)
Universidade Federal de Minas Gerais (BR)
Conselho Nacional de Desenvolvimento Científico e Tecnológico, Financiadora de Estudos e Projetos, Fundação de Amparo à Pesquisa do Estado de Minas Gerais
Clean water and sanitation
Openalex Percentile: Top 59%
Crystal structures of chemical compounds
0.16
DOISourceOpenAlex
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Coordination structure and intermolecular interactions in copper(II) acetate complexes with 1,10-phenanthroline and 2,2′-bipyridine — Leonardo H. R. Dos Santos, Bernardo L. Rodrigues, et al. · Acta Crystallographica Section C Structural Chemistry (2024) | TGRS Research Map | TGRS